Enhanced Li-O battery performance using NiS/MoS heterostructure by building internal electric field to promote the one-electron oxygen reduction/oxidation.

Electrocatalysts with appropriate electron coupling toward LiO intermediates can exhibit superior oxygen reduction/evolution reaction kinetics in Li-O batteries (LOBs). In this work, a charge redistribution strategy has been developed by constructing NiS/MoS heterostructure nanosheet self-assembled hollow microspheres with an internal electric field to regulate the interaction with LiO and then improve the electrochemical performance of LOBs. Density functional theory calculations and physicochemical characterizations reveal that the difference of work functions between NiS and MoS promotes the electron redistribution in heterointerface via built-in electrical field, leading to increased electron density of interfacial Ni atom, thereby enhancing its electron coupling toward LiO intermediates and promoting one-electron oxygen reduction/oxidation reaction kinetics. As a result, the NiS/MoS-based LOBs exhibit evidently higher discharge capacity and much better cycling performance than the batteries using NiS and MoS. This work provides a reliable charge redistribution strategy induced by build-in electric field to design efficient catalysts for LOBs.