Adams Lewis J, Matthews Peter D, Morbec Juliana M, Balakrishnan Nilanthy
School of Chemical and Physical Sciences, Keele University, Keele ST5 5BG, United Kingdom.
Nanotechnology. 2024 Jul 11;35(39). doi: 10.1088/1361-6528/ad5dc1.
Transition metal dichalcogenides have been extensively studied in recent years because of their fascinating optical, electrical, and catalytic properties. However, low-cost, scalable production remains a challenge. Aerosol-assisted chemical vapor deposition (AACVD) provides a new method for scalable thin film growth. In this study, we demonstrate the growth of molybdenum disulfide (MoS) thin films using AACVD method. This method proves its suitability for low-temperature growth of MoSthin films on various substrates, such as glass, silicon dioxide, quartz, silicon, hexagonal boron nitride, and highly ordered pyrolytic graphite. The as-grown MoSshows evidence of substrate-induced strain. The type of strain and the morphology of the as-grown MoShighly depend on the growth substrate's surface roughness, crystallinity, and chemical reactivity. Moreover, the as-grown MoSshows the presence of both direct and indirect band gaps, suitable for exploitation in future electronics and optoelectronics.
近年来,过渡金属二硫属化物因其迷人的光学、电学和催化性能而受到广泛研究。然而,低成本、可扩展的生产仍然是一个挑战。气溶胶辅助化学气相沉积(AACVD)为可扩展的薄膜生长提供了一种新方法。在本研究中,我们展示了使用AACVD方法生长二硫化钼(MoS)薄膜。该方法证明了其适用于在各种衬底上低温生长MoS薄膜,如玻璃、二氧化硅、石英、硅、六方氮化硼和高度有序热解石墨。生长的MoS显示出衬底诱导应变的证据。应变类型和生长的MoS的形态高度依赖于生长衬底的表面粗糙度、结晶度和化学反应性。此外,生长的MoS显示出直接和间接带隙的存在,适用于未来电子学和光电子学的开发。