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气溶胶辅助化学气相沉积生长的二硫化钼中的衬底诱导应变。

Substrate-induced strain in molybdenum disulfide grown by aerosol-assisted chemical vapor deposition.

作者信息

Adams Lewis J, Matthews Peter D, Morbec Juliana M, Balakrishnan Nilanthy

机构信息

School of Chemical and Physical Sciences, Keele University, Keele ST5 5BG, United Kingdom.

出版信息

Nanotechnology. 2024 Jul 11;35(39). doi: 10.1088/1361-6528/ad5dc1.

Abstract

Transition metal dichalcogenides have been extensively studied in recent years because of their fascinating optical, electrical, and catalytic properties. However, low-cost, scalable production remains a challenge. Aerosol-assisted chemical vapor deposition (AACVD) provides a new method for scalable thin film growth. In this study, we demonstrate the growth of molybdenum disulfide (MoS) thin films using AACVD method. This method proves its suitability for low-temperature growth of MoSthin films on various substrates, such as glass, silicon dioxide, quartz, silicon, hexagonal boron nitride, and highly ordered pyrolytic graphite. The as-grown MoSshows evidence of substrate-induced strain. The type of strain and the morphology of the as-grown MoShighly depend on the growth substrate's surface roughness, crystallinity, and chemical reactivity. Moreover, the as-grown MoSshows the presence of both direct and indirect band gaps, suitable for exploitation in future electronics and optoelectronics.

摘要

近年来,过渡金属二硫属化物因其迷人的光学、电学和催化性能而受到广泛研究。然而,低成本、可扩展的生产仍然是一个挑战。气溶胶辅助化学气相沉积(AACVD)为可扩展的薄膜生长提供了一种新方法。在本研究中,我们展示了使用AACVD方法生长二硫化钼(MoS)薄膜。该方法证明了其适用于在各种衬底上低温生长MoS薄膜,如玻璃、二氧化硅、石英、硅、六方氮化硼和高度有序热解石墨。生长的MoS显示出衬底诱导应变的证据。应变类型和生长的MoS的形态高度依赖于生长衬底的表面粗糙度、结晶度和化学反应性。此外,生长的MoS显示出直接和间接带隙的存在,适用于未来电子学和光电子学的开发。

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