Chauhan Kalpana, Singh Prem, Sen Kshipra, Singhal Rakesh Kumar, Thakur Vijay Kumar
Chemistry under School of Engineering and Technology, Central University of Haryana, Mahendragarh, Haryana 123031, India.
Shoolini University, Solan, Himachal Pradesh 173229, India.
ACS Omega. 2024 Jun 17;9(26):27766-27788. doi: 10.1021/acsomega.3c09713. eCollection 2024 Jul 2.
Water remediation, acknowledged as a significant scientific topic, guarantees the safety of drinking water, considering the diverse range of pollutants that can contaminate it. Among these pollutants, arsenic stands out as a particularly severe threat to human health, significantly compromising the overall quality of life. Despite widespread awareness of the harmful effects of arsenic poisoning, there remains a scarcity of literature on the utilization of biobased polymers as sustainable alternatives for comprehensive arsenic removal in practical concern. Cellulose and chitosan, two of the most prevalent biopolymers in nature, provide a wide range of potential benefits in cutting-edge industries, including water remediation. Nanocomposites derived from cellulose and chitosan offer numerous advantages over their larger equivalents, including high chelating properties, cost-effective production, strength, integrity during usage, and the potential to close the recycling loop. Within the sphere of arsenic remediation, this Review outlines the selection criteria for novel cellulose/chitosan-nanocomposites, such as scalability in synthesis, complete arsenic removal, and recyclability for technical significance. Especially, it aims to give an overview of the historical development of research in cellulose and chitosan, techniques for enhancing their performance, the current state of the art of the field, and the mechanisms underlying the adsorption of arsenic using cellulose/chitosan nanocomposites. Additionally, it extensively discusses the impact of shape and size on adsorbent efficiency, highlighting the crucial role of physical characteristics in optimizing performance for practical applications. Furthermore, this Review addresses regeneration, reuse, and future prospects for chitosan/cellulose-nanocomposites, which bear practical relevance. Therefore, this Review underscores the significant research gap and offers insights into refining the structural features of adsorbents to improve total inorganic arsenic removal, thereby facilitating the transition of green-material-based technology into operational use.
水修复被公认为一个重要的科学课题,鉴于可能污染饮用水的污染物种类繁多,它能确保饮用水的安全。在这些污染物中,砷对人类健康构成了特别严重的威胁,严重影响了整体生活质量。尽管人们普遍意识到砷中毒的有害影响,但关于在实际应用中利用生物基聚合物作为全面去除砷的可持续替代品的文献仍然匮乏。纤维素和壳聚糖是自然界中最普遍的两种生物聚合物,在包括水修复在内的前沿行业中具有广泛的潜在益处。由纤维素和壳聚糖衍生的纳米复合材料比其较大的同类材料具有许多优势,包括高螯合性能、经济高效的生产、强度、使用过程中的完整性以及闭合回收循环的潜力。在砷修复领域,本综述概述了新型纤维素/壳聚糖纳米复合材料的选择标准,如合成的可扩展性、完全去除砷以及技术意义上的可回收性。特别是,它旨在概述纤维素和壳聚糖的研究历史发展、提高其性能的技术、该领域的当前技术水平以及使用纤维素/壳聚糖纳米复合材料吸附砷的潜在机制。此外,它广泛讨论了形状和尺寸对吸附剂效率的影响,强调了物理特性在优化实际应用性能方面的关键作用。此外,本综述还涉及壳聚糖/纤维素纳米复合材料的再生、再利用和未来前景,这些具有实际相关性。因此,本综述强调了重大的研究差距,并提供了有关改进吸附剂结构特征以提高总无机砷去除率的见解,从而促进基于绿色材料的技术向实际应用的转变。