Dong Yanhong, Feng Yange, Wang Daoai
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences Lanzhou 730000 China
Qingdao Center of Resource Chemistry and New Materials Qingdao 266104 China.
Chem Sci. 2024 May 27;15(27):10436-10447. doi: 10.1039/d4sc01432d. eCollection 2024 Jul 10.
Preparing nanostructured surfaces has been considered an effective method to improve the output of triboelectric nanogenerators (TENGs), but how to quickly prepare materials with a nanostructured surface for TENGs has always been a challenge. Here, polypropylene nanowires and electrospun nylon 11 nanofibers were successfully prepared through a simple and time-saving method with a high success rate. Compared with a flat TENG, the output performance of a dual nanostructured TENG is enhanced by more than 5 times. After 1,1,2,2-perfluorooctyl trichlorosilane was assembled on the surface of the polypropylene film, the dual nanostructured TENG achieved the maximum output with the short-circuit current, output voltage, and charge density of 63.3 μA, 1135 V and 161.5 μC m, respectively. Compared with a planar structured TENG, the short-circuit current and output voltage were enhanced by about 18 times, and the charge density was increased by about 36 times. In addition, the TENG showed good working stability with almost no decrease in output after continuous operation for 193 000 cycles. The electricity generated by this TENG can successfully light up 1280 LEDs and continuously power a multi-functional electronic watch. Finally, the triboelectric signal generated by this TENG was used to control an optocoupler switch, indicating good application prospects in a remote control switching circuit.
制备纳米结构表面被认为是提高摩擦电纳米发电机(TENGs)输出的有效方法,但如何快速制备具有纳米结构表面的TENGs材料一直是一个挑战。在此,通过一种简单且省时的方法成功制备了聚丙烯纳米线和静电纺丝尼龙11纳米纤维,成功率很高。与平面TENG相比,双纳米结构TENG的输出性能提高了5倍以上。在聚丙烯膜表面组装1,1,2,2-全氟辛基三氯硅烷后,双纳米结构TENG实现了最大输出,短路电流、输出电压和电荷密度分别为63.3 μA、1135 V和161.5 μC m。与平面结构TENG相比,短路电流和输出电压提高了约18倍,电荷密度增加了约36倍。此外,TENG表现出良好的工作稳定性,连续运行193000次循环后输出几乎没有下降。该TENG产生的电能能够成功点亮1280个发光二极管,并持续为一块多功能电子手表供电。最后,该TENG产生的摩擦电信号被用于控制光耦合器开关,表明其在遥控开关电路中具有良好的应用前景。