Key Laboratory of Clean Pulp & Papermaking and Pollution Control of Guangxi, College of Light Industrial and Food Engineering, Guangxi University, Nanning 530004, China.
State Key Laboratory of Biobased Materials and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China.
Int J Mol Sci. 2024 Nov 8;25(22):11992. doi: 10.3390/ijms252211992.
Furfural is a renewable platform compound that can be derived from lignocellulosic biomass. The highly functionalized molecular structure of furfural enables us to prepare a variety of high value-added chemicals, which will help realize biomass high-value utilization, and alleviate energy and environmental problems. This paper reviews the research progress on furfural production and upgrading to C5 chemicals from the catalyst perspective. The emphasis is placed on summarizing and refining the catalytic mechanism and in-depth analysis of available data. Specifically, the reaction mechanism of furfural production and upgrading is summarized firstly from the perspective of reaction pathways and reaction kinetics. Then, the available data are further processed to evaluate the actual reaction efficiency of different catalytic systems from multiple dimensions. Finally, based on statistical analysis, the challenges and opportunities of furfural-based research are proposed.
糠醛是一种可再生的平台化合物,可以从木质纤维素生物质中提取。糠醛的高度官能化分子结构使我们能够制备各种高附加值化学品,这将有助于实现生物质的高值化利用,缓解能源和环境问题。本文从催化剂的角度综述了糠醛制备和升级为 C5 化学品的研究进展。重点在于总结和提炼催化机制,并对现有数据进行深入分析。具体来说,首先从反应途径和反应动力学的角度总结了糠醛的生产和升级反应机制。然后,进一步处理可用数据,从多个维度评估不同催化体系的实际反应效率。最后,基于统计分析,提出了糠醛研究的挑战和机遇。