Flexible Resistive Gas Sensor Based on Molybdenum Disulfide-Modified Polypyrrole for Trace NO Detection.

High sensitivity and selectivity and short response and recovery times are important for practical conductive polymer gas sensors. However, poor stability, poor selectivity, and long response times significantly limit the applicability of single-phase conducting polymers, such as polypyrrole (PPy). In this study, PPy/MoS composite films were prepared via chemical polymerization and mechanical blending, and flexible thin-film resistive NO sensors consisting of copper heating, fluorene polyester insulating, and PPy/MoS sensing layers with a silver fork finger electrode were fabricated on a flexible polyimide substrate using a flexible electronic printer. The PPy/MoS composite films were characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, and field-emission scanning electron microscopy. A home-built gas sensing test platform was built to determine the resistance changes in the composite thin-film sensor with temperature and gas concentration. The PPy/MoS sensor exhibited better sensitivity, selectivity, and stability than a pure PPy sensor. Its response to 50 ppm NO was 38% at 150 °C, i.e., 26% higher than that of the pure PPy sensor, and its selectivity and stability were also higher. The greater sensitivity was attributed to p-n heterojunction formation after MoS doping and more gas adsorption sites. Thus, PPy/MoS composite film sensors have good application prospects.