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商用表面声波无线电通信滤波器作为DMMP传感器换能器的应用

The Application of Commercial Surface Acoustic Wave Radio Communication Filters as Transducers for DMMP Sensors.

作者信息

Grabka Michał, Jasek Krzysztof, Pasternak Mateusz, Witkiewicz Zygfryd

机构信息

Faculty of Advanced Technologies and Chemistry, Military University of Technology, 00-908 Warsaw, Poland.

Faculty of Electronics, Military University of Technology, 00-908 Warsaw, Poland.

出版信息

Sensors (Basel). 2024 Jul 2;24(13):4299. doi: 10.3390/s24134299.

Abstract

In the present study, we used two popular radio communication SAW resonators as a base for gas sensors and tested their performance. Taking into account issues related to sensor sensitivity, the possibility of applying a sensor layer, the availability of devices, and other related issues, we selected two popular single-port resonators with center frequencies of 315 and 433 MHz (models R315 and R433, respectively) for testing purposes. Both resonators were equipped with a sensitive film of hexafluoroisopropanol-substituted polydimethylsiloxane, a material that selectively absorbs molecules with a high ability to form basic hydrogen bonds. Fabricated sensors were used to detect trace amounts of dimethyl methylphosphonate (DMMP) vapor, which has often been used in similar studies as a nerve chemical warfare agent simulant. Sensors using both devices loaded with sensor layers of an optimal thickness rapidly reacted to a gas containing DMMP at a concentration of 3 mg/m, generating a stable analytical signal ranging from several to several dozen kilohertz. In the case of R433, the frequency signal was 20.5 kHz at 1 min from the beginning of exposure to DMMP. The obtained results showed that the used transducers exhibited good performance as a base for gas sensors. Finally, their suitability for sensing applications was confirmed by a comparison with the results obtained in previous similar studies.

摘要

在本研究中,我们使用了两种常见的射频通信声表面波谐振器作为气体传感器的基础,并测试了它们的性能。考虑到与传感器灵敏度、应用传感器层的可能性、设备的可用性以及其他相关问题,我们选择了两种中心频率分别为315和433 MHz的常见单端口谐振器(分别为R315和R433型号)用于测试。两种谐振器都配备了六氟异丙醇取代的聚二甲基硅氧烷敏感膜,该材料能选择性地吸收具有高形成碱性氢键能力的分子。制造的传感器用于检测痕量的甲基膦酸二甲酯(DMMP)蒸气,在类似研究中,DMMP常被用作神经化学战剂模拟物。使用两种加载了最佳厚度传感器层的设备的传感器,对浓度为3 mg/m的含DMMP气体迅速做出反应,产生了几到几十千赫兹的稳定分析信号。对于R433,从开始暴露于DMMP起1分钟时频率信号为20.5 kHz。所得结果表明,所使用的换能器作为气体传感器的基础表现出良好的性能。最后,通过与先前类似研究中获得的结果进行比较,证实了它们在传感应用中的适用性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b92d/11244062/b0249f5495df/sensors-24-04299-g001.jpg

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