Zhang Min, Han Yi, Liu Ting, Jia Hongguang
School of Physics Science and Technology, Xinjiang University, Urumqi 830046, China.
College of Chemistry, Xinjiang University, Urumqi 830046, China.
Sensors (Basel). 2024 Jul 3;24(13):4320. doi: 10.3390/s24134320.
High temperature represents a critical constraint in the development of gas sensors. Therefore, investigating gas sensors operating at room temperature holds significant practical importance. In this study, coal-based porous carbon (C-700) and coal-based C/MoO nanohybrid materials were synthesized using a simple one-step vapor deposition and sintering method, and their gas-sensing performance was investigated. The gas-sensing performance for several VOC gases (phenol, ethyl acetate, ethanol, acetone, triethylamine, and toluene) and a 95% RH high-humidity environment were tested. The results indicated that the C/MoO-450 sample sintered at 450 °C exhibited excellent specific selectivity towards acetone at room temperature, with a response value of 4153.09% and response/recovery times of 10.8 s and 2.9 s, respectively. Furthermore, the C/MoO-450 sample also demonstrated good repeatability and long-term stability. The sensing mechanism of the synthesized materials was also explored. The superior gas-sensing performance can be attributed to the synergistic effect between the porous carbon and MoO nanoparticles. Given the importance of enhancing the high-tech and high-value-added utilization of coal, this study provides a viable approach for utilizing coal-based carbon materials in detecting volatile organic compounds at room temperature.
高温是气体传感器发展中的一个关键限制因素。因此,研究室温下工作的气体传感器具有重要的实际意义。在本研究中,采用简单的一步气相沉积和烧结法合成了煤基多孔碳(C-700)和煤基C/MoO纳米杂化材料,并对其气敏性能进行了研究。测试了几种挥发性有机化合物气体(苯酚、乙酸乙酯、乙醇、丙酮、三乙胺和甲苯)以及95%相对湿度的高湿度环境下的气敏性能。结果表明,在450℃烧结的C/MoO-450样品在室温下对丙酮表现出优异的选择性,响应值为4153.09%,响应/恢复时间分别为10.8秒和2.9秒。此外,C/MoO-450样品还具有良好的重复性和长期稳定性。还探讨了合成材料的传感机制。优异的气敏性能可归因于多孔碳与MoO纳米颗粒之间的协同效应。鉴于提高煤炭高科技、高附加值利用的重要性,本研究为利用煤基碳材料在室温下检测挥发性有机化合物提供了一种可行的方法。