• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

磁性姜黄素-铜氧化石墨烯作为制备聚氢喹啉和亚砜的简便且可回收的多相纳米催化剂。

Magnetic curcumin-copper graphene oxide as facile and recyclable heterogeneous nanocatalyst for preparation of polyhydroquinolines and sulfoxides.

作者信息

Gharehkhani Alireza, Hajjami Maryam

机构信息

Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran.

出版信息

Sci Rep. 2024 Jul 23;14(1):16937. doi: 10.1038/s41598-024-67876-z.

DOI:10.1038/s41598-024-67876-z
PMID:39043853
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11266393/
Abstract

In this research project, a versatile procedure has been designed for the preparation of supported copper@curcumin on magnetic graphene oxide nanoparticles (GO@FeO@Cur-Cu). The structure of prepared nanocatalyst was characterized by several techniques including; Fourier transform infrared, powder X-ray diffraction, thermal gravimetric analysis, energy dispersive X-ray analysis, inductively coupled plasma optical emission spectroscopy, vibrating sample magnetometer, transmission electron microscopy, and scanning electron microscopy analyses. The catalytic properties of GO@FeO@Cur-Cu were examined for the efficient synthesis of polyhydroquinolines as well as the preparation of sulfoxides through selective oxidation of sulfides in the presence of hydrogen peroxide.

摘要

在本研究项目中，设计了一种通用方法来制备负载型铜@姜黄素磁性氧化石墨烯纳米颗粒（GO@FeO@Cur-Cu）。通过多种技术对制备的纳米催化剂结构进行了表征，包括傅里叶变换红外光谱、粉末X射线衍射、热重分析、能量色散X射线分析、电感耦合等离子体发射光谱、振动样品磁强计、透射电子显微镜和扫描电子显微镜分析。研究了GO@FeO@Cur-Cu在高效合成多氢喹啉以及在过氧化氢存在下通过硫化物的选择性氧化制备亚砜方面的催化性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/7154e134c4b4/41598_2024_67876_Fig18_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/50a178c09454/41598_2024_67876_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/333a857df1fc/41598_2024_67876_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/bf638dd6cc95/41598_2024_67876_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/f7f5609d06f2/41598_2024_67876_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/84e0bb2fadd8/41598_2024_67876_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/352bd359cae2/41598_2024_67876_Fig6a_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/d2d62eaa471f/41598_2024_67876_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/00e56a767c80/41598_2024_67876_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/58f63536dd7d/41598_2024_67876_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/6cb3f7507430/41598_2024_67876_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/b62d4f0c35d3/41598_2024_67876_Fig11_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/b06fbced7821/41598_2024_67876_Fig12_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/82f939ed4603/41598_2024_67876_Fig13_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/374ba8d3e0a5/41598_2024_67876_Fig14_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/6518f69ee4fb/41598_2024_67876_Fig15_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/0e8a529e2682/41598_2024_67876_Fig16_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/cf2f95cb38c5/41598_2024_67876_Fig17_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/7154e134c4b4/41598_2024_67876_Fig18_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/50a178c09454/41598_2024_67876_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/333a857df1fc/41598_2024_67876_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/bf638dd6cc95/41598_2024_67876_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/f7f5609d06f2/41598_2024_67876_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/84e0bb2fadd8/41598_2024_67876_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/352bd359cae2/41598_2024_67876_Fig6a_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/d2d62eaa471f/41598_2024_67876_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/00e56a767c80/41598_2024_67876_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/58f63536dd7d/41598_2024_67876_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/6cb3f7507430/41598_2024_67876_Fig10_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/b62d4f0c35d3/41598_2024_67876_Fig11_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/b06fbced7821/41598_2024_67876_Fig12_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/82f939ed4603/41598_2024_67876_Fig13_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/374ba8d3e0a5/41598_2024_67876_Fig14_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/6518f69ee4fb/41598_2024_67876_Fig15_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/0e8a529e2682/41598_2024_67876_Fig16_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/cf2f95cb38c5/41598_2024_67876_Fig17_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/7154e134c4b4/41598_2024_67876_Fig18_HTML.jpg

相似文献

1
Magnetic curcumin-copper graphene oxide as facile and recyclable heterogeneous nanocatalyst for preparation of polyhydroquinolines and sulfoxides.磁性姜黄素-铜氧化石墨烯作为制备聚氢喹啉和亚砜的简便且可回收的多相纳米催化剂。
Sci Rep. 2024 Jul 23;14(1):16937. doi: 10.1038/s41598-024-67876-z.
2
Mo@GAA-FeO MNPs: a highly efficient and environmentally friendly heterogeneous magnetic nanocatalyst for the synthesis of polyhydroquinoline derivatives.钼@GAA-氧化铁磁性纳米颗粒：一种用于合成聚氢喹啉衍生物的高效且环保的多相磁性纳米催化剂。
RSC Adv. 2021 Mar 11;11(18):10497-10511. doi: 10.1039/d1ra00396h. eCollection 2021 Mar 10.
3
Magnetically separable and recyclable FeO@SiO/isoniazide/Pd nanocatalyst for highly efficient synthesis of biaryls by Suzuki coupling reactions.磁性可分离和可回收的 FeO@SiO₂/异烟肼/Pd 纳米催化剂用于通过 Suzuki 偶联反应高效合成联芳烃。
J Colloid Interface Sci. 2017 Sep 1;501:175-184. doi: 10.1016/j.jcis.2017.04.054. Epub 2017 Apr 20.
4
Magnetization of graphene oxide nanosheets using nickel magnetic nanoparticles as a novel support for the fabrication of copper as a practical, selective, and reusable nanocatalyst in C-C and C-O coupling reactions.使用镍磁性纳米颗粒对氧化石墨烯纳米片进行磁化，以此作为一种新型载体，用于制备在C-C和C-O偶联反应中实用、选择性高且可重复使用的铜纳米催化剂。
RSC Adv. 2021 Jul 27;11(42):25867-25879. doi: 10.1039/d1ra03578a.
5
Phenyl and ionic liquid based bifunctional periodic mesoporous organosilica supported copper: An efficient nanocatalyst for clean production of polyhydroquinolines.基于苯基和离子液体的双功能介孔有机硅负载铜：一种用于清洁生产多氢喹啉的高效纳米催化剂。
J Colloid Interface Sci. 2017 Nov 1;505:1177-1184. doi: 10.1016/j.jcis.2017.07.010. Epub 2017 Jul 3.
6
Design, Preparation and Characterization of MoO3H-functionalized Fe3O4@SiO2 Magnetic Nanocatalyst and Application for the One-pot Multicomponent Reactions.MoO₃H功能化的Fe₃O₄@SiO₂磁性纳米催化剂的设计、制备与表征及其在一锅多组分反应中的应用
Acta Chim Slov. 2017 Sep;64(3):707-713. doi: 10.17344/acsi.2017.3208.
7
Ultrasound-Promoted preparation and application of novel bifunctional core/shell FeO@SiO@PTS-APG as a robust catalyst in the expeditious synthesis of Hantzsch esters.超声促进制备新型核壳结构 FeO@SiO@PTS-APG 并将其作为一种坚固的催化剂在快速合成 Hantzsch 酯中的应用。
Sci Rep. 2023 May 17;13(1):8016. doi: 10.1038/s41598-023-33990-7.
8
Preparation, Antibacterial Activity, and Catalytic Application of Magnetic Graphene Oxide-Fucoidan in the Synthesis of 1,4-Dihydropyridines and Polyhydroquinolines.磁性石墨烯氧化物-褐藻糖胶的制备、抗菌活性及其在 1,4-二氢吡啶和多羟基喹啉合成中的催化应用。
ChemistryOpen. 2021 Dec;10(12):1186-1196. doi: 10.1002/open.202100221.
9
Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles.合成磁性聚苯乙烯负载的含 Cu(II)杂环配合物作为一种可分离和可重复使用的催化剂，用于制备 N-磺酰基-N-芳基四唑。
Sci Rep. 2023 Feb 24;13(1):3214. doi: 10.1038/s41598-023-30198-7.
10
Cellulose matrix embedded copper decorated magnetic bionanocomposite as a green catalyst in the synthesis of dihydropyridines and polyhydroquinolines.纤维素基质嵌入铜修饰磁性生物纳米复合材料作为一种绿色催化剂在二氢吡啶和多氢喹啉的合成中的应用。
Carbohydr Polym. 2019 Mar 15;208:251-260. doi: 10.1016/j.carbpol.2018.12.069. Epub 2018 Dec 22.

引用本文的文献

1
Curcumin-Based Nanoparticles: Advancements and Challenges in Tumor Therapy.基于姜黄素的纳米颗粒：肿瘤治疗的进展与挑战
Pharmaceutics. 2025 Jan 15;17(1):114. doi: 10.3390/pharmaceutics17010114.
2
Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst.在一种坚固的生物废弃物骨炭-布朗斯特固体酸催化剂上高效合成嘧啶-5-腈衍生物。
Sci Rep. 2024 Dec 6;14(1):30411. doi: 10.1038/s41598-024-82040-3.

本文引用的文献

1
A binary dumbbell visible light driven photocatalyst for simultaneous hydrogen production with the selective oxidation of benzyl alcohol to benzaldehyde.一种用于同时产氢以及将苯甲醇选择性氧化为苯甲醛的二元哑铃状可见光驱动光催化剂。
J Colloid Interface Sci. 2024 Jul;665:911-921. doi: 10.1016/j.jcis.2024.03.190. Epub 2024 Mar 29.
2
Schottky junction enhanced H evolution for graphitic carbon nitride-NiS composite photocatalysts.肖特基结增强石墨相氮化碳-硫化镍复合光催化剂的析氢性能
J Colloid Interface Sci. 2024 Mar;657:133-141. doi: 10.1016/j.jcis.2023.11.092. Epub 2023 Nov 17.
3
Efficient oxidation of sulfides to sulfoxides catalyzed by heterogeneous Zr-containing polyoxometalate grafted on graphene oxide.
负载于氧化石墨烯上的多相含锆多金属氧酸盐催化硫化物高效氧化为亚砜
Sci Rep. 2023 Oct 5;13(1):16752. doi: 10.1038/s41598-023-43985-z.
4
Preparation and catalytic application of two different nanocatalysts based on hexagonal mesoporous silica (HMS) in synthesis of tetrahydrobenzo[b]pyran and 1,4-dihydropyrano[2,3-c]pyrazole derivatives.基于六方介孔硅（HMS）的两种不同纳米催化剂的制备及其在合成四氢苯并[b]吡喃和 1,4-二氢吡喃并[2,3-c]吡唑衍生物中的催化应用。
Sci Rep. 2022 Dec 21;12(1):22108. doi: 10.1038/s41598-022-26605-0.
5
One-pot in-situ hydrothermal synthesis of ternary InS/NbO/NbC Schottky/S-scheme integrated heterojunction for efficient photocatalytic hydrogen production.一锅原位水热合成三元InS/NbO/NbC肖特基/S型复合异质结用于高效光催化产氢
J Colloid Interface Sci. 2022 Dec 15;628(Pt B):500-512. doi: 10.1016/j.jcis.2022.08.071. Epub 2022 Aug 17.
6
Silica sulfuric acid coated on SnFeO MNPs: synthesis, characterization and catalytic applications in the synthesis of polyhydroquinolines.负载于锡铁氧体磁性纳米颗粒上的硅胶硫酸：合成、表征及其在多氢喹啉合成中的催化应用
RSC Adv. 2022 May 12;12(23):14397-14410. doi: 10.1039/d2ra01202b.
7
Magnetization of graphene oxide nanosheets using nickel magnetic nanoparticles as a novel support for the fabrication of copper as a practical, selective, and reusable nanocatalyst in C-C and C-O coupling reactions.使用镍磁性纳米颗粒对氧化石墨烯纳米片进行磁化，以此作为一种新型载体，用于制备在C-C和C-O偶联反应中实用、选择性高且可重复使用的铜纳米催化剂。
RSC Adv. 2021 Jul 27;11(42):25867-25879. doi: 10.1039/d1ra03578a.
8
Synthesis and characterization of novel hercynite@sulfuric acid and its catalytic applications in the synthesis of polyhydroquinolines and 2,3-dihydroquinazolin-4(1)-ones.新型铁尖晶石@硫酸的合成、表征及其在多氢喹啉和2,3-二氢喹唑啉-4(1)-酮合成中的催化应用
RSC Adv. 2022 Jan 20;12(5):2770-2787. doi: 10.1039/d1ra07381h. eCollection 2022 Jan 18.
9
Synthesis of Curcumin Nanoparticles from Raw Turmeric Rhizome.从新鲜姜黄根茎中合成姜黄素纳米颗粒。
ACS Omega. 2021 Mar 18;6(12):8246-8252. doi: 10.1021/acsomega.0c06314. eCollection 2021 Mar 30.
10
Layered double hydroxides as heterogeneous catalyst systems in the cross-coupling reactions: an overview.层状双氢氧化物作为交叉偶联反应中的多相催化剂体系：概述。
Mol Divers. 2022 Feb;26(1):569-587. doi: 10.1007/s11030-020-10170-7. Epub 2021 Jan 4.