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磁性姜黄素-铜氧化石墨烯作为制备聚氢喹啉和亚砜的简便且可回收的多相纳米催化剂。

Magnetic curcumin-copper graphene oxide as facile and recyclable heterogeneous nanocatalyst for preparation of polyhydroquinolines and sulfoxides.

作者信息

Gharehkhani Alireza, Hajjami Maryam

机构信息

Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, 6517838683, Iran.

出版信息

Sci Rep. 2024 Jul 23;14(1):16937. doi: 10.1038/s41598-024-67876-z.

Abstract

In this research project, a versatile procedure has been designed for the preparation of supported copper@curcumin on magnetic graphene oxide nanoparticles (GO@FeO@Cur-Cu). The structure of prepared nanocatalyst was characterized by several techniques including; Fourier transform infrared, powder X-ray diffraction, thermal gravimetric analysis, energy dispersive X-ray analysis, inductively coupled plasma optical emission spectroscopy, vibrating sample magnetometer, transmission electron microscopy, and scanning electron microscopy analyses. The catalytic properties of GO@FeO@Cur-Cu were examined for the efficient synthesis of polyhydroquinolines as well as the preparation of sulfoxides through selective oxidation of sulfides in the presence of hydrogen peroxide.

摘要

在本研究项目中,设计了一种通用方法来制备负载型铜@姜黄素磁性氧化石墨烯纳米颗粒(GO@FeO@Cur-Cu)。通过多种技术对制备的纳米催化剂结构进行了表征,包括傅里叶变换红外光谱、粉末X射线衍射、热重分析、能量色散X射线分析、电感耦合等离子体发射光谱、振动样品磁强计、透射电子显微镜和扫描电子显微镜分析。研究了GO@FeO@Cur-Cu在高效合成多氢喹啉以及在过氧化氢存在下通过硫化物的选择性氧化制备亚砜方面的催化性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7621/11266393/50a178c09454/41598_2024_67876_Fig1_HTML.jpg

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