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对船体喷水除锈废水中源自防污漆的微塑料进行定性和定量评估及其向海洋环境的排放

Qualitative and quantitative assessment of microplastics derived from antifouling paint in effluent from ship hull hydroblasting and their emission into the marine environment.

作者信息

Kim Taekhyun, Eo Soeun, Shim Won Joon, Kim Moonkoo

机构信息

Risk Assessment Research Center, Korea Institute of Ocean Science and Technology, Geoje 53201, Republic of Korea; Department of Ocean Science, University of Science and Technology, Daejeon 34113, Republic of Korea.

Risk Assessment Research Center, Korea Institute of Ocean Science and Technology, Geoje 53201, Republic of Korea.

出版信息

J Hazard Mater. 2024 Sep 15;477:135258. doi: 10.1016/j.jhazmat.2024.135258. Epub 2024 Jul 18.

Abstract

This study focused on microplastic (MP) contamination originating from ship paint, particularly during the hydroblasting of ship hull, to understand the emission characteristics of MPs into the marine environment. We evaluated paint particles generated from the hydroblasting of an ocean-going vessel based on their number, size, polymer type, and mass. Hydroblasting a vessel produced 4.3 × 10 particles, predominantly comprising acrylic particles, 99.9 % of which were smaller than 5 mm. Of the 44.1 kg of antifouling (AF) paint particles generated, 36.5 kg consisted of particles smaller than 5 mm, with 18.2 kg being identified as plastic emissions. Furthermore, we calculated the MP emission factor (8.43 g/m) for hydroblasting on AF paint by dividing the total emission by the wetted surface area (WSA) of the vessel. This factor was then extrapolated by multiplying it with the total WSA of global ships and their hull cleaning frequency to preliminarily estimate the annual global MP emissions. Consequently, a total of 665.6 tons of plastics was generated globally by hydroblasting, with approximately 550.2 tons of these being in the form of MPs. This study highlights the need for developing stricter regulations governing hydroblasting operations and waste disposal practices to protect marine environments from MP pollution.

摘要

本研究聚焦于源自船舶涂料的微塑料(MP)污染,特别是在船体水力喷射过程中的污染,以了解微塑料向海洋环境中的排放特征。我们基于远洋船舶水力喷射产生的涂料颗粒的数量、尺寸、聚合物类型和质量进行了评估。对一艘船舶进行水力喷射产生了4.3×10个颗粒,主要由丙烯酸颗粒组成,其中99.9%的颗粒小于5毫米。在产生的44.1千克防污(AF)涂料颗粒中,36.5千克由小于5毫米的颗粒组成,其中18.2千克被确定为塑料排放物。此外,我们通过将总排放量除以船舶的湿表面积(WSA),计算出了AF涂料水力喷射的微塑料排放因子(8.43克/平方米)。然后,将该因子乘以全球船舶的总湿表面积及其船体清洁频率进行外推,以初步估算全球微塑料的年排放量。因此,水力喷射在全球共产生了665.6吨塑料,其中约550.2吨为微塑料形式。本研究强调需要制定更严格的法规来管理水力喷射作业和废物处理做法,以保护海洋环境免受微塑料污染。

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