Dong L R, Zhang J, Li Y Z, Gao Y X, Wang M, Huang M X, Wang J S, Chen K X
MOE Key Laboratory of Advanced Functional Materials, College of Materials Science and Engineering, Beijing University of Technology, Chaoyang District, Beijing 100124, China.
Advanced Structural Ceramics Innovation Center, YongJiang Laboratory, Ningbo 315202, China.
Science. 2024 Jul 26;385(6707):422-427. doi: 10.1126/science.adp0559. Epub 2024 Jul 25.
The inherent brittleness of ceramics, primarily due to restricted atomic motions from rigid ionic or covalent bonded structures, is a persistent challenge. This characteristic hinders dislocation nucleation in ceramics, thereby impeding the enhancement of plasticity through a dislocation-engineering strategy commonly used in metals. Finding a strategy that continuously generates dislocations within ceramics may enhance plasticity. Here, we propose a "borrowing-dislocations" strategy that uses a tailored interfacial structure with well-ordered bonds. Such an approach enables ceramics to have greatly improved tensile ductility by mobilizing a considerable number of dislocations in ceramic borrowed from metal through the interface, thereby overcoming the challenge associated with direct dislocation nucleation within ceramics. This strategy provides a way to enhance tensile ductility in ceramics.
陶瓷固有的脆性主要源于刚性离子键或共价键结构限制了原子运动,这一直是个挑战。这种特性阻碍了陶瓷中位错的形核,从而妨碍了通过金属中常用的位错工程策略来提高塑性。找到一种能在陶瓷中持续产生位错的策略可能会提高塑性。在此,我们提出一种“借位错”策略,该策略利用具有有序键的定制界面结构。这种方法能使陶瓷通过界面从金属借取大量位错,从而极大地提高拉伸延展性,进而克服与陶瓷内部直接位错形核相关的挑战。此策略提供了一种提高陶瓷拉伸延展性的方法。