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锌掺杂对0.5BZT-0.5BCT材料的结构、相变及电学性能的影响。

The effect of Zn doping on the structure, phase transformation and electric properties of 0.5BZT-0.5BCT materials.

作者信息

Huang Ling

机构信息

School of Science, XiJing University, Xi'an, 710123, China.

College of Chemistry and Materials, Weinan Normal University, Weinan 714000, China.

出版信息

Heliyon. 2024 Jul 3;10(13):e33845. doi: 10.1016/j.heliyon.2024.e33845. eCollection 2024 Jul 15.

Abstract

In the current study, an improved method of adding Zn ion doping to the 0.5BZT-0.5BCT-based films with high pyroelectric properties was designed. Under different Zn ion doping ratios, the structure, dielectric constant, phase transition relationship and other characteristics of the test product were analyzed experimentally to obtain the optimal ratio parameters. The experimental results demonstrate that the dielectric properties of the 0.5BZT-0.5BCT-xZn-based films proposed in this study can be far superior to those of other films under the optimal preparation process. The optimal dielectric properties and ferroelectric properties are obtained when the doped data are 0.008. Considering the comprehensive dielectric and energy storage capacity, the optimal doping ratio is 0.01, which can take into account dielectric data and energy storage performance. The energy storage density is 1.842 , and the energy storage efficiency exceeds 30%. From 0 to 0.02, the properties of the material, such as the hysteresis loop and phase transition relationship are excellent. The properties of the materials studied in this study are excellent, and they are excellent candidate materials for the future application of ferroelectric materials, and provide ideas for related work.

摘要

在当前研究中,设计了一种改进方法,即在具有高热电性能的0.5BZT - 0.5BCT基薄膜中添加锌离子掺杂。在不同的锌离子掺杂比例下,对测试产品的结构、介电常数、相变关系等特性进行了实验分析,以获得最佳比例参数。实验结果表明,在最佳制备工艺下,本研究提出的0.5BZT - 0.5BCT - xZn基薄膜的介电性能可远优于其他薄膜。当掺杂数据为0.008时,可获得最佳介电性能和铁电性能。综合考虑介电和储能能力,最佳掺杂比例为0.01,此时可兼顾介电数据和储能性能。储能密度为1.842 ,储能效率超过30%。从0到0.02,材料的性能,如磁滞回线和相变关系都很优异。本研究中所研究材料的性能优异,是铁电材料未来应用的优秀候选材料,并为相关工作提供了思路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2991/11279252/c52b53a929e6/gr001.jpg

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