菲咯硼烷的合成以及通过形式上的氮烯插入反应制备氮杂硼芘。
Synthesis of phenanthrylboroles and formal nitrene insertion to access azaborapyrenes.
作者信息
Zacharias Harie, Begum Ayesha, Han Jianhua, Bartholome Tyler A, Marder Todd B, Martin Caleb D
机构信息
Department of Chemistry and Biochemistry, Baylor University, One Bear Place #97348, Waco, Texas 76798, USA.
Institut für Anorganische Chemie, and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
出版信息
Chem Commun (Camb). 2024 Aug 13;60(66):8740-8743. doi: 10.1039/d4cc02863e.
Extended conjugation has been introduced into boroles but only on the 2,3- or 4,5-positions of the central BC core. In this work we synthesize phenanthrylboroles that also have conjugation on the 3,4-positions and demonstrate their insertion reactivity with azides to furnish B,N-analogues of pyrene.
扩展共轭已被引入到硼杂环戊二烯中，但仅在中心硼碳核心的2,3-或4,5-位上。在这项工作中，我们合成了在3,4-位上也具有共轭的菲基硼杂环戊二烯，并证明了它们与叠氮化物的插入反应活性，以提供芘的硼氮类似物。
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