García-Limón Víctor, Aguilar-Mejía Oscar E, Reyes-Cruz Hector, Suaste-Gómez Ernesto
Department of Electrical Engineering, Section Bioelectronics, Center for Research and Advanced Studies (CINVESTAV), Mexico City, Mexico.
PLoS One. 2024 Aug 1;19(8):e0308026. doi: 10.1371/journal.pone.0308026. eCollection 2024.
Electrospinning is a process in which high voltage creates nanostructured fibers with random orientation from a polymer solution. A novel electrospinning instrument was designed and constructed, capable of orienting and collimating the trajectory of the electrified fluid jet. The equipment collimates and adjusts the electrified fluid jet in the X-Y directions using deflector plates connected to a variable electric field. Simultaneously, different membrane thicknesses can be selected, i.e., in the Z direction. Additionally, by programming the sinusoidal function generator to perform an X-Y sweep, Lissajous figures (LF) were obtained. SEM images obtained through XYZ electrospinning of PVC and PVDF membranes were used to determine the control achieved over the orientation distribution of the processed nanofibers and the modification of their diameter, with and without applying the electric field to the deflector plates. The nanofibers obtained from the polymeric membranes, which originated after the straight segment of the Taylor cone, did not exhibit a random trajectory and position. Instead, the collimated electrified fluid jet deposited them in a cross pattern (X-Y) on the collector-cathode plate.
静电纺丝是一种通过高压从聚合物溶液中制造出具有随机取向的纳米结构纤维的过程。设计并构建了一种新型静电纺丝仪器,该仪器能够使带电流体射流的轨迹定向和准直。该设备使用连接到可变电场的偏转板在X-Y方向上对准和调整带电流体射流。同时,可以在Z方向上选择不同的膜厚度。此外,通过对正弦函数发生器进行编程以执行X-Y扫描,获得了李萨如图形(LF)。通过对PVC和PVDF膜进行XYZ静电纺丝获得的扫描电子显微镜(SEM)图像,用于确定在对偏转板施加电场和不施加电场的情况下,对加工的纳米纤维取向分布及其直径变化的控制效果。从聚合物膜中获得的纳米纤维,这些纳米纤维源自泰勒锥的直线段之后,并未呈现出随机的轨迹和位置。相反,准直的带电流体射流将它们以交叉图案(X-Y)沉积在集电极-阴极板上。