College of Environment, Zhejiang University of Technology, Hangzhou 310032, China.
Trinity Consultants, Inc. (China office), Hangzhou 310012, China.
J Environ Sci (China). 2025 Feb;148:126-138. doi: 10.1016/j.jes.2023.09.001. Epub 2023 Sep 11.
Severe ground-level ozone (O) pollution over major Chinese cities has become one of the most challenging problems, which have deleterious effects on human health and the sustainability of society. This study explored the spatiotemporal distribution characteristics of ground-level O and its precursors based on conventional pollutant and meteorological monitoring data in Zhejiang Province from 2016 to 2021. Then, a high-performance convolutional neural network (CNN) model was established by expanding the moment and the concentration variations to general factors. Finally, the response mechanism of O to the variation with crucial influencing factors is explored by controlling variables and interpolating target variables. The results indicated that the annual average MDA8-90 concentrations in Zhejiang Province are higher in the northern and lower in the southern. When the wind direction (WD) ranges from east to southwest and the wind speed (WS) ranges between 2 and 3 m/sec, higher O concentration prone to occur. At different temperatures (T), the O concentration showed a trend of first increasing and subsequently decreasing with increasing NO concentration, peaks at the NO concentration around 0.02 mg/m. The sensitivity of NO to O formation is not easily affected by temperature, barometric pressure and dew point temperature. Additionally, there is a minimum [Formula: see text] at each temperature when the NO concentration is 0.03 mg/m, and this minimum [Formula: see text] decreases with increasing temperature. The study explores the response mechanism of O with the change of driving variables, which can provide a scientific foundation and methodological support for the targeted management of O pollution.
中国主要城市的严重地面臭氧 (O) 污染已成为最具挑战性的问题之一,对人类健康和社会的可持续性造成了有害影响。本研究基于 2016 年至 2021 年浙江省常规污染物和气象监测数据,探讨了地面 O 及其前体物的时空分布特征。然后,通过扩展矩和浓度变化来扩展常规因素,建立了高性能卷积神经网络 (CNN) 模型。最后,通过控制变量和插值目标变量,探讨了 O 对关键影响因素变化的响应机制。结果表明,浙江省的年平均 MDA8-90 浓度在北部较高,在南部较低。当风向 (WD) 范围为东到西南,风速 (WS) 范围在 2 到 3 米/秒之间时,较高的 O 浓度容易发生。在不同的温度 (T) 下,随着 NO 浓度的增加,O 浓度呈先增加后减少的趋势,在 NO 浓度约为 0.02mg/m 时达到峰值。NO 对 O 形成的敏感性不易受温度、气压和露点温度的影响。此外,当 NO 浓度为 0.03mg/m 时,在每个温度下都存在最小 [Formula: see text],并且随着温度的升高,最小 [Formula: see text] 减小。本研究探讨了 O 随驱动变量变化的响应机制,为 O 污染的有针对性管理提供了科学基础和方法支持。