采用转移主导的支化自由基端粒化（TBRT）和原子转移自由基聚合（ATRP）来形成具有正交引发的复合聚酯-聚甲基丙烯酸酯支化-线性星形共聚物杂化物。
Employing transfer-dominated branching radical telomerisation (TBRT) and atom transfer radical polymerisation (ATRP) to form complex polyester-polymethacrylate branched-linear star copolymer hybrids orthogonal initiation.
作者信息
Dwyer Andrew B, Sandy William, Hern Faye Y, Penrhyn-Lowe Oliver B, McKeating Samuel, Flynn Sean, Wright Stephen, Pate Sophie, Chambon Pierre, Rannard Steve P
机构信息
Department of Chemistry, University of Liverpool, Crown Street, L69 7ZD, UK.
Materials Innovation Factory, University of Liverpool, Crown Street, L69 7ZD, UK.
出版信息
Chem Commun (Camb). 2024 Sep 12;60(74):10116-10119. doi: 10.1039/d4cc02142h.
TBRT and ATRP are orthogonal initiation chemistries used in vinyl polymerisations. Here, we present the first combination of these techniques to readily create high molecular weight branched polyester macroinitiators capable of forming star copolymers from a range of methacrylate monomers.
TBRT和ATRP是用于乙烯基聚合的正交引发化学方法。在此，我们展示了这些技术的首次组合，以便轻松制备能够从一系列甲基丙烯酸酯单体形成星形共聚物的高分子量支化聚酯大分子引发剂。
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