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双[（η-丁基-环戊二烯基）三羰基钼（I）](-)的晶体结构

Crystal structure of bis-[(η--butyl-cyclo-pentadien-yl)tri-carbonyl-molybdenum(I)](-).

作者信息

Ibrahimova Nigar Z, Tagiyev Dilgam B, Lyatifov Iltifat U, Akkurt Mehmet, Hasanov Khudayar I, Bhattarai Ajaya

机构信息

Acad. M. Nagiev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Azerbaijan Republic, Azerbaijan.

Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Türkiye.

出版信息

Acta Crystallogr E Crystallogr Commun. 2024 Jul 23;80(Pt 8):882-885. doi: 10.1107/S2056989024006959. eCollection 2024 Aug 1.

DOI:10.1107/S2056989024006959
PMID:39108783
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11299755/
Abstract

The dinuclear mol-ecule of the title compound, [Mo(CH)(CO)] or [Mo( BuCp)(CO)] where Bu and Cp are -butyl and cyclo-penta-dienyl, is centrosymmetric and is characterized by an Mo-Mo bond length of 3.2323 (3) Å. Imposed by inversion symmetry, the BuCp and the carbonyl ligands are in a arrangement to each other. In the crystal, inter-molecular C-H⋯O contacts lead to the formation of layers parallel to the plane.

摘要

标题化合物[Mo(CH)(CO)]或[Mo( BuCp)(CO)]（其中 Bu和Cp分别为正丁基和环戊二烯基）的双核分子具有中心对称性，其特征在于Mo-Mo键长为3.2323(3) Å。由于反演对称性， BuCp和羰基配体彼此呈 排列。在晶体中，分子间的C-H⋯O接触导致形成与 平面平行的层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/1db83a41c71f/e-80-00882-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/7b3dfadde035/e-80-00882-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/28d5cc5e7df5/e-80-00882-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/c425bc598792/e-80-00882-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/81b6a13c9f7a/e-80-00882-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/1db83a41c71f/e-80-00882-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/7b3dfadde035/e-80-00882-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/28d5cc5e7df5/e-80-00882-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/c425bc598792/e-80-00882-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/81b6a13c9f7a/e-80-00882-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/918d/11299755/1db83a41c71f/e-80-00882-fig5.jpg

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