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去除有毒六价铬的氧化石墨烯纳米颗粒:动力学、等温线及热力学研究

Removal of toxic hexavalent chromium graphene oxide nanoparticles: study of kinetics, isotherms, and thermodynamics.

作者信息

Khdoor Zohor, Makharza Sami, Qurie Mohannad, Fohely Firas, Abu Taha Abdallah, Hampel Silke

机构信息

Faculty of Science and Technology, Department of Chemistry, Hebron University P. O. Box 40 Hebron West Bank Palestine.

College of Medicine, Hebron University P. O. Box 40 Hebron West Bank Palestine

出版信息

RSC Adv. 2024 Aug 5;14(34):24345-24351. doi: 10.1039/d4ra03697b.

Abstract

In this study, graphene oxide (GO) was prepared by the Hummers' method from graphite material. The adsorption potential of GO-200 nm for the removal of Cr(vi) ions was investigated. Fourier transform infrared (FTIR) spectroscopy was used to analyze Cr(vi) before and after adsorption. The adsorption isotherm was fitted by the Langmuir model and the maximum adsorption capacity of the GO was 41.27 mg g at 25 °C. Thermodynamic parameters (Δ°), (Δ°), and (Δ°) were calculated and exhibited as +2.63 kJ mol K, +4.30 kJ mol K, and +5.56 kJ mol K at 30 mg L of Cr(vi) solution, respectively.

摘要

在本研究中,采用Hummers法由石墨材料制备氧化石墨烯(GO)。研究了200nm的GO对去除Cr(Ⅵ)离子的吸附潜力。利用傅里叶变换红外(FTIR)光谱对吸附前后的Cr(Ⅵ)进行分析。吸附等温线用Langmuir模型拟合,25℃时GO的最大吸附容量为41.27mg/g。在30mg/L的Cr(Ⅵ)溶液中,分别计算得到热力学参数(Δ°)、(Δ°)和(Δ°),其值分别为+2.63kJ/mol·K、+4.30kJ/mol·K和+5.56kJ/mol·K。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c238/11298974/3b43b55dc5e2/d4ra03697b-s1.jpg

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