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水溶性席夫碱配体和金属配合物：基于绿色溶剂的概述

Water-soluble Schiff base ligands and metal complexes: an overview considering green solvent.

作者信息

Islam Md Tariqul, Bitu Nur Amin, Chaki Bijan Mohon, Hossain Md Jakir, Asraf Md Ali, Hossen Md Faruk, Kudrat-E-Zahan Md, Latif Md Abdul

机构信息

Department of Chemistry, Rajshahi University Rajshahi 6205 Bangladesh

Department of Chemistry, Begum Rokeya University Rangpur Bangladesh

出版信息

RSC Adv. 2024 Aug 13;14(35):25256-25272. doi: 10.1039/d4ra04310c. eCollection 2024 Aug 12.

DOI:10.1039/d4ra04310c
PMID:39139233
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11320196/
Abstract

The water-soluble metal complexes with Schiff base (SB) ligands are of great interest to green chemistry researchers due to their stability, cost-effectiveness, eco-friendly, electron-donating ability, and various applications. They have high potential to express their biological activity including anti-inflammatory, anticancer, antibacterial, antifungal, antioxidant, and DNA binding and cleavage. In the recent era, transition metal complexes have played a significant role in different processes such as hydrogenation, carbonylation, oxidation, reduction, epoxidation, hydrolysis, decomposition, and polymerization reactions in industry. However, their limited aqueous solubility may be the major limitation to their potential catalytic, industrial, and clinical applications. In industrial catalytic processes, it has been proven that water can be used as a solvent to minimize the environmental effect of different reactions as well as simple and complete separation. Water is a green solvent, flexible, non-toxic, safe, readily available, environmentally harmless, and inexpensive. Attaching different substituents on Schiff bases enhances the water solubility and catalytic activity. Studies on water-soluble SB complexes will explore these aspects and their prospects for the future evolution of their diverse applications.

摘要

含有席夫碱（SB）配体的水溶性金属配合物因其稳定性、成本效益、环境友好性、给电子能力以及各种应用而备受绿色化学研究人员的关注。它们具有很高的潜力来展现其生物活性，包括抗炎、抗癌、抗菌、抗真菌、抗氧化以及DNA结合和裂解活性。在最近的时代，过渡金属配合物在工业中的不同过程，如氢化、羰基化、氧化、还原、环氧化、水解、分解和聚合反应中发挥了重要作用。然而，它们有限的水溶性可能是其潜在催化、工业和临床应用的主要限制。在工业催化过程中，已证明水可作为溶剂，以尽量减少不同反应对环境的影响以及实现简单而完全的分离。水是一种绿色溶剂，具有灵活性、无毒、安全、易于获取、对环境无害且价格低廉。在席夫碱上连接不同的取代基可提高水溶性和催化活性。对水溶性席夫碱配合物的研究将探索这些方面及其在未来多样化应用发展中的前景。

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