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光酶催化的电子自旋共振分析

Electron spin resonance analysis of photoenzymatic catalysis.

作者信息

Yu Lu, Tian Changlin

机构信息

High Magnetic Field Laboratory, Hefei Institutes of Physical Science, Chinese Academy of Sciences, China.

Division of Life Sciences and Medicine, University of Science and Technology of China, China.

出版信息

Natl Sci Rev. 2024 Mar 14;11(9):nwae095. doi: 10.1093/nsr/nwae095. eCollection 2024 Sep.

Abstract

This Perspective highlights recent research progress and prospects in elucidating the catalytic mechanism of photoenzymes using ESR (electron spin resonance) spectroscopy, which is emerging as a unique and crucial method for identifying radical intermediates, illustrating electron transfer events and the underlying mechanisms of photoenzymatic catalysis.

摘要

这篇展望文章重点介绍了利用电子自旋共振(ESR)光谱阐明光酶催化机制的最新研究进展和前景。ESR光谱正成为一种独特且关键的方法,用于识别自由基中间体、阐释电子转移事件以及光酶催化的潜在机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a5c2/11321245/a1b7f6c19780/nwae095fig1.jpg

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