可见光促进的双环[1.1.0]丁烷的德 Mayo 型反应。
Visible Light Promoted de Mayo Type Reaction of Bicyclo[1.1.0]butanes.
作者信息
Yang Chunming, Hu Minmin, Hu Chaoqin, Mi Xueling, Luo Sanzhong
机构信息
Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
College of Chemistry, Beijing Normal University, Beijing, 1000875, China.
出版信息
Chemistry. 2024 Dec 5;30(68):e202402965. doi: 10.1002/chem.202402965. Epub 2024 Oct 16.
PMID:39174490
Abstract
We reported herein a visible light mediated de Mayo-type reaction between 1,3-diketones and BCB. The reaction proceeds through a [2π+2σ] cycloaddition and retro-aldol sequence, producing cis-difunctionalized cyclobutanes in high yields with good regio- and diastereoselectivity.
摘要
我们在此报道了1,3 - 二酮与BCB之间的可见光介导的德 Mayo 型反应。该反应通过[2π + 2σ]环加成和逆羟醛缩合序列进行，以高收率、良好的区域和非对映选择性生成顺式双官能化环丁烷。
Zotero 插件