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挠曲电、摩擦电和自由界面电荷。

Flexoelectricity, Triboelectricity, and Free Interfacial Charges.

作者信息

Marks L D, Olson K P

机构信息

Department of Materials Science and Engineering, Northwestern University, Evanston, IL, 60208, USA.

出版信息

Small. 2024 Aug 25:e2310546. doi: 10.1002/smll.202310546.

DOI:10.1002/smll.202310546
PMID:39183520
Abstract

Triboelectricity has been a topic of some confusion for many years, probably because it is very diverse and some of the fundamental science has not been clear. This is now starting to change. A few years ago, the importance of flexoelectricity at asperities is pointed out. That paper exploited the established physics of compensation of bound surface or interfacial charges without going into detail. The purpose of this paper is to expand further on this, mapping from the established physics of electrostatics with contact potentials and Maxwell's displacement field to the underlying fundamentals of charge transfer in triboelectricity. Examples from the published literature are used to illustrate this. In the discussion, some of the open questions and challenges to the community are mentioned.

摘要

多年来,摩擦电一直是一个存在一些混淆的话题,可能是因为它非常多样化,而且一些基础科学尚未明确。现在这种情况开始有所改变。几年前,人们指出了粗糙表面处挠曲电的重要性。那篇论文利用了已确立的关于束缚表面或界面电荷补偿的物理学原理,但没有深入细节。本文的目的是在此基础上进一步拓展,从具有接触电势和麦克斯韦位移场的静电学既定物理学原理,映射到摩擦电中电荷转移的潜在基本原理。文中引用了已发表文献中的例子来说明这一点。在讨论部分,还提到了该领域一些尚未解决的问题和挑战。

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本文引用的文献

1
When Flexoelectricity Drives Triboelectricity.当 Flexoelectricity 驱动 Triboelectricity 时。
Nano Lett. 2022 May 25;22(10):3939-3945. doi: 10.1021/acs.nanolett.2c00240. Epub 2022 May 16.
2
Band Bending and Ratcheting Explain Triboelectricity in a Flexoelectric Contact Diode.能带弯曲和棘轮效应解释了柔性电接触二极管中的摩擦电现象。
Nano Lett. 2022 May 25;22(10):3914-3921. doi: 10.1021/acs.nanolett.2c00107. Epub 2022 May 6.
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Nonadiabatic Born Effective Charges in Metals and the Drude Weight.金属中的非绝热玻恩有效电荷与德鲁德权重
Phys Rev Lett. 2022 Mar 4;128(9):095901. doi: 10.1103/PhysRevLett.128.095901.
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Mixed Triboelectric and Flexoelectric Charge Transfer at the Nanoscale.纳米尺度下的混合摩擦电和挠曲电电荷转移。
Adv Sci (Weinh). 2021 Oct;8(20):e2101793. doi: 10.1002/advs.202101793. Epub 2021 Aug 13.
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Triboelectric Nanogenerator: Structure, Mechanism, and Applications.摩擦纳米发电机:结构、机制与应用
ACS Nano. 2021 Jan 26;15(1):258-287. doi: 10.1021/acsnano.0c09803. Epub 2021 Jan 11.
6
Quantifying and understanding the triboelectric series of inorganic non-metallic materials.量化并理解无机非金属材料的摩擦电序列。
Nat Commun. 2020 Apr 29;11(1):2093. doi: 10.1038/s41467-020-15926-1.
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Does Flexoelectricity Drive Triboelectricity?柔性电致伸缩是否能驱动摩擦起电?
Phys Rev Lett. 2019 Sep 13;123(11):116103. doi: 10.1103/PhysRevLett.123.116103.
8
Converse flexoelectricity yields large piezoresponse force microscopy signals in non-piezoelectric materials.逆 flexoelectricity 在非压电材料中产生大的压电力显微镜信号。
Nat Commun. 2019 Mar 20;10(1):1266. doi: 10.1038/s41467-019-09266-y.
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Contact-Electrification between Two Identical Materials: Curvature Effect.两种相同材料之间的接触起电:曲率效应。
ACS Nano. 2019 Feb 26;13(2):2034-2041. doi: 10.1021/acsnano.8b08533. Epub 2019 Feb 5.
10
Direct Observation of Large Flexoelectric Bending at the Nanoscale in Lanthanide Scandates.镧系 Scandates 中纳米级大挠曲电弯曲的直接观测。
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