Elaissaoui Ines, Sayeb Soumaya, Ounif Ibtissem, Ferhi Mounir, Karima Horchani-Naifer, Ennigrou Dorra Jellouli
Physical Chemistry Laboratory of Mineral Materials and Their Applications, National Center for Research in Materials Sciences, Technopark Borj Cedria, P.O. Box: 73-8027, Soliman, Tunisia.
Laboratory of Water, Membrane and Environmental Biotechnology, Centre of Research and Water Technologies, Technopark of Borj-Cedria, BP 273, 8020, Soliman, Tunisia.
Heliyon. 2024 Jun 8;10(12):e32552. doi: 10.1016/j.heliyon.2024.e32552. eCollection 2024 Jun 30.
Development of nanofiber membranes with the ability to remove organic dye such as Indigo Carmine (IC) from effluent wastewater is of immense help to the textile industry. In the present study, we investigate the preparation of cellulose acetate (CA) nanofiber membranes with optimized performances using electrospinning technique for effective removal of Indigo Carmine (IC) dye. Electrospinning parameters and solvent system containing acetic acid were adjusted to obtain CA nanofibers membranes which better suits dye removal application. The obtained nanofiber membranes were characterized using Scanning Electron Microscopy (SEM), Fourier-Transform Infrared Spectroscopy (FT-IR) and contact angle analysis. Results show that nanofiber webs with optimized electrospinning parameters were continuously formed and are substantially free of defects such as beading, with an average diameter of 950 ± 50 nm. Hydrophobicity of membranes were successfully modified and showed important increase of contact angle values from 37° to 107°. The stirring time was varied to improve the solution homogeneity and consequently the response of membranes in filtration treatment. The CA membranes performance was evaluated through water flux and permeability measurement and tested on IC dye removal. The results showed a rate of dye removal around 83 % and a maximum adsorption capacity (Q) of 13.09 mg/g for the optimized CA membranes.
开发具有从印染废水中去除靛蓝胭脂红(IC)等有机染料能力的纳米纤维膜对纺织工业有极大帮助。在本研究中,我们使用静电纺丝技术研究了具有优化性能的醋酸纤维素(CA)纳米纤维膜的制备,以有效去除靛蓝胭脂红(IC)染料。调整静电纺丝参数和含乙酸的溶剂体系,以获得更适合染料去除应用的CA纳米纤维膜。使用扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)和接触角分析对所得纳米纤维膜进行表征。结果表明,具有优化静电纺丝参数的纳米纤维网连续形成,基本无珠状等缺陷,平均直径为950±50nm。成功改变了膜的疏水性,接触角值从37°显著增加到107°。改变搅拌时间以提高溶液均匀性,从而改善膜在过滤处理中的响应。通过水通量和渗透率测量评估CA膜的性能,并测试其对IC染料的去除效果。结果表明,优化后的CA膜对染料的去除率约为83%,最大吸附容量(Q)为13.09mg/g。