Department of Chemistry, State Key Lab of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, China.
Chem Soc Rev. 2014 Aug 21;43(16):6116-40. doi: 10.1039/c4cs00159a.
Metal-organic framework (MOF) materials, which are constructed from metal ions or metal ion clusters and bridging organic linkers, exhibit regular crystalline lattices with relatively well-defined pore structures and interesting properties. As a new class of porous solid materials, MOFs are attractive for a variety of industrial applications including separation membranes - a rapidly developing research area. Many reports have discussed the synthesis and applications of MOFs and MOF thin films, but relatively few have addressed MOF membranes. This critical review provides an overview of the diverse MOF membranes that have been prepared, beginning with a brief introduction to the current techniques for the fabrication of MOF membranes. Gas and liquid separation applications with different MOF membranes are also included (175 references).
金属-有机骨架（MOF）材料由金属离子或金属离子簇和桥连有机配体构建，具有规则的晶体格子和相对明确的孔结构以及有趣的性质。作为一类新型的多孔固体材料，MOFs 在多种工业应用中具有吸引力，包括分离膜 - 这是一个快速发展的研究领域。许多报告讨论了 MOFs 和 MOF 薄膜的合成和应用，但相对较少涉及 MOF 膜。本综述性评论提供了对各种 MOF 膜的概述，首先简要介绍了 MOF 膜的当前制备技术。还包括不同 MOF 膜的气体和液体分离应用（175 篇参考文献）。
