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基于碳硼烷的晶体多孔材料的最新进展

Recent Advances in Carborane-Based Crystalline Porous Materials.

作者信息

Meng Yuxuan, Lin Xi, Huang Jinyi, Zhang Liangliang

机构信息

Strait Institute of Flexible Electronics (SIFE, Future Technologies), Fujian Key Laboratory of Flexible Electronics, Fujian Normal University and Strait Laboratory of Flexible Electronics (SLo-FE), Fuzhou 350017, China.

Frontiers Science Center for Flexible Electronics (FSCFE), MIIT Key Laboratory of Flexible Electronics (KLoFE), Northwestern Polytechnical University, Xi'an 710072, China.

出版信息

Molecules. 2024 Aug 19;29(16):3916. doi: 10.3390/molecules29163916.

DOI:10.3390/molecules29163916
PMID:39202996
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11357283/
Abstract

The field of carborane research has witnessed continuous development, leading to the construction and development of a diverse range of crystalline porous materials for various applications. Moreover, innovative synthetic approaches are expanding in this field. Since the first report of carborane-based crystalline porous materials (CCPMs) in 2007, the synthesis of carborane ligands, particularly through innovative methods, has consistently posed a significant challenge in discovering new structures of CCPMs. This paper provides a comprehensive summary of recent advances in various synthetic approaches for CCPMs, along with their applications in different domains. The primary challenges and future opportunities are expected to stimulate further multidisciplinary development in the field of CCPMs.

摘要

碳硼烷研究领域不断发展,催生了用于各种应用的多种晶态多孔材料的构建与发展。此外,创新的合成方法也在该领域不断涌现。自2007年首次报道基于碳硼烷的晶态多孔材料(CCPMs)以来,碳硼烷配体的合成,尤其是通过创新方法进行的合成,在发现CCPMs新结构方面一直是一项重大挑战。本文全面总结了CCPMs各种合成方法的最新进展及其在不同领域的应用。预计主要挑战和未来机遇将推动CCPMs领域进一步的多学科发展。

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本文引用的文献

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A novel hydrophobic carborane-hybrid microporous material for reversed CH adsorption and efficient CH/CH separation under humid conditions.一种新型疏水性碳硼烷杂化微孔材料,用于在潮湿条件下进行反向CH吸附和高效CH/CH分离。
Chem Sci. 2024 Mar 12;15(15):5653-5659. doi: 10.1039/d4sc00424h. eCollection 2024 Apr 17.
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Carborane-Based Three-Dimensional Covalent Organic Frameworks.基于碳硼烷的三维共价有机框架
J Am Chem Soc. 2023 Nov 8;145(44):24202-24209. doi: 10.1021/jacs.3c08541. Epub 2023 Oct 27.
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Robust Carborane-Based Metal-Organic Frameworks for Hexane Separation.
用于己烷分离的坚固的碳硼烷基金属有机框架材料。
J Am Chem Soc. 2023 Nov 1;145(43):23433-23441. doi: 10.1021/jacs.3c04641. Epub 2023 Oct 20.
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Composites and Materials Prepared from Boron Cluster Anions and Carboranes.由硼簇阴离子和碳硼烷制备的复合材料及材料
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