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基于紫外可见光谱的改进增强和自注意力径向基函数网络用于化学需氧量预测

Improved boosting and self-attention RBF networks for COD prediction based on UV-vis.

作者信息

Chen Xi'ang, Wang Senlin, Chen Hao, Fan Renhao

机构信息

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350005, China.

University of Chinese Academy of Sciences, Beijing 100049, China.

出版信息

Anal Methods. 2024 Sep 26;16(37):6383-6391. doi: 10.1039/d4ay01441c.

Abstract

Chemical Oxygen Demand (COD) is crucial for assessing water quality. Compared to traditional chemical detection methods, UV-vis spectroscopy for measuring COD offers advantages such as speed, reduced consumption of materials, and no secondary pollution. Considering the impact of suspended particles in water, this paper proposes an optimized boosting model based on a combination strategy for turbidity compensation, using absorption spectra obtained from reservoir water samples UV-vis. A self-attention mechanism is introduced into the radial basis function (RBF) network, resulting in a COD detection model based on the saRBF framework. This model facilitates comprehensive optimization of the entire process, from turbidity compensation of the original absorption spectrum to the subsequent COD prediction. Experimental results show that the proposed COD measurement model achieves a coefficient of determination of 0.9267, a root mean square error of 1.2669, and a mean absolute error of 1.0097, outperforming other COD measurement models. This work provides a new approach for turbidity compensation and COD detection research.

摘要

化学需氧量(COD)对于评估水质至关重要。与传统化学检测方法相比,利用紫外可见光谱法测量COD具有速度快、材料消耗少且无二次污染等优点。考虑到水中悬浮颗粒的影响,本文提出了一种基于浊度补偿组合策略的优化增强模型,该模型使用从水库水样的紫外可见吸收光谱。将自注意力机制引入径向基函数(RBF)网络,得到基于saRBF框架的COD检测模型。该模型有助于对从原始吸收光谱的浊度补偿到后续COD预测的整个过程进行全面优化。实验结果表明,所提出的COD测量模型的决定系数为0.9267,均方根误差为1.2669,平均绝对误差为1.0097,优于其他COD测量模型。这项工作为浊度补偿和COD检测研究提供了一种新方法。

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