Schweicher Guillaume, Das Susobhan, Resel Roland, Geerts Yves
Université Libre de Bruxelles (ULB), Faculté des Sciences, Laboratoire de chimie des polyméres, Boulevard du Triomphe, 1050 Bruxelles, Belgium.
Institute of Solid State Physics, Graz University of Technology, Petersgasse 16, 8010 Graz, Austria.
Acta Crystallogr C Struct Chem. 2024 Oct 1;80(Pt 10):601-611. doi: 10.1107/S2053229624008283. Epub 2024 Sep 4.
Historically, knowledge of the molecular packing within the crystal structures of organic semiconductors has been instrumental in understanding their solid-state electronic properties. Nowadays, crystal structures are thus becoming increasingly important for enabling engineering properties, understanding polymorphism in bulk and in thin films, exploring dynamics and elucidating phase-transition mechanisms. This review article introduces the most salient and recent results of the field.
从历史上看，了解有机半导体晶体结构中的分子堆积情况对于理解其固态电子特性至关重要。如今，晶体结构对于实现工程特性、理解块状和薄膜中的多晶型现象、探索动力学以及阐明相变机制变得越来越重要。本文综述介绍了该领域最显著和最新的研究成果。
