二氯化四（3-甲氧基苯胺）镍（II）
Di-chloridotetra-kis-(3-meth-oxy-aniline)nickel(II).
作者信息
Mukda Benjamin A, Dickie Diane A, Turnbull Mark M
机构信息
Carlson School of Chemistry and Biochemistry, Clark University, 950 Main St., Worcester, MA 01610, USA.
Department of Chemistry, University of Virginia, 409 McCormack Rd., Charlottesville, VA 22904, USA.
出版信息
IUCrdata. 2024 Aug 13;9(Pt 8):x240776. doi: 10.1107/S2414314624007764. eCollection 2024 Aug.
The reaction of nickel(II) chloride with 3-meth-oxy-aniline yielded di-chlorido-tetra-kis-(3-meth-oxy-aniline)nickel(II), [NiCl(CHNO)], as yellow crystals. The Ni ion is pseudo-octa-hedral with the chloride ions to each other. The four 3-meth-oxy-aniline ligands differ primarily due to different conformations about the Ni-N bond, which also affect the hydrogen bonding. Inter-molecular N-H⋯ Cl hydrogen bonds and short Cl⋯Cl contacts between mol-ecules link them into chains parallel to the axis.
氯化镍（II）与3-甲氧基苯胺反应生成二氯-四-（3-甲氧基苯胺）镍（II），[NiCl(CHNO)]，为黄色晶体。镍离子呈假八面体构型，氯离子相互相对。四个3-甲氧基苯胺配体主要因围绕Ni-N键的不同构象而有所不同，这也影响了氢键。分子间的N-H⋯Cl氢键以及分子间短的Cl⋯Cl接触将它们连接成平行于轴的链。
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