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揭示冷榨油在紫外线照射下的氧化稳定性、植物化学物质丰富度和营养完整性。

Unveiling the oxidative stability, phytochemical richness, and nutritional integrity of cold-pressed oil under UV exposure.

作者信息

Belhoussaine Oumayma, El Kourchi Chaimae, Mohammed Amakhmakh, El Yadini Adil, Ullah Riaz, Iqbal Zafar, Goh Khang Wen, Gallo Monica, Harhar Hicham, Bouyahya Abdelhakim, Tabyaoui Mohamed

机构信息

Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University in Rabat, Av. Ibn Battouta, B.P1014 Rabat, Morocco.

Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology, Sidi Mohamed ben Abdellah University in Fes, Morocco.

出版信息

Food Chem X. 2024 Aug 30;24:101785. doi: 10.1016/j.fochx.2024.101785. eCollection 2024 Dec 30.

Abstract

This study examines the effect of UV irradiation on the oxidation stability of oil, presenting possible changes in the phytochemical profile due to photo-oxidation. GC-MS analysis of the oils identified 11 fatty acid compounds with a high percentage of unsaturated fatty acids, the most important of which is -linolenic acid (ALA), known as omega-3 (48.88 %), also significant profiles of phytosterol and tcocopherol isomers rich in -Sitosterol and -tocopherols respectively. As well as physicochemical properties such as free fatty acids (FFA %), peroxide value (PV) and iodine value (IV), and nutritional indexes that determine the significant changes observed during the oxidation process, the most important of which is the progressive increase in acidity, peroxide, conjugated dienes and trienes and degrees of unsaturation over 8 h of UV exposure. High levels of carotenoids and phenolic compounds (TPC) protect and enhance oil quality in the face of irradiation, so a significantly small difference is observed between irradiated and non-irradiated oil during photo-oxidation.

摘要

本研究考察了紫外线照射对油脂氧化稳定性的影响,呈现了因光氧化作用导致的植物化学特征可能发生的变化。对油脂进行气相色谱 - 质谱(GC - MS)分析,鉴定出11种脂肪酸化合物,其中不饱和脂肪酸比例较高,最重要的是γ-亚麻酸(ALA),即ω-3(含量为48.88%),同时还发现了分别富含β-谷甾醇和γ-生育酚的植物甾醇和生育酚异构体的显著特征。除了游离脂肪酸(FFA%)、过氧化值(PV)和碘值(IV)等物理化学性质,以及确定氧化过程中观察到的显著变化的营养指标外,最重要的是在紫外线照射8小时内,酸度、过氧化物、共轭二烯和三烯以及不饱和度逐渐增加。高水平的类胡萝卜素和酚类化合物(TPC)在面对辐射时能保护并提高油脂质量,因此在光氧化过程中,照射过的油脂和未照射的油脂之间观察到的差异非常小。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d056/11406365/2620a29993d5/ga1.jpg

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