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太阳光诱导生物活性化合物的合成。

Solar Light-induced Synthesis of Biologically Active Compounds.

作者信息

Das Aparna, Ray Devalina, Ashraf Muhammad Waqar, Banik Bimal Krishna

机构信息

Department of Mathematics and Natural Sciences, College of Sciences and Human Studies, Prince Mohammad Bin Fahd University, Al Khobar, 31952, Kingdom of Saudi Arabia.

Amity Institute of Biotechnology, Amity University, Noida, Uttar Pradesh, India.

出版信息

Curr Top Med Chem. 2025;25(7):761-778. doi: 10.2174/0115680266318635240906102108.

DOI:10.2174/0115680266318635240906102108
PMID:39297469
Abstract

Over the past few years, photocatalytic methods have shown great promise as low-cost, environmentally friendly, and sustainable technologies. During the development of photochemistry, a variety of sources of light were used, including sunlight, compact fluorescent lamps, lasers, and even light-emitting diodes. As a part of preparing diverse organic compounds, the photochemical approach was used, for instance, to form rings, arylated compounds, cycloaddition, functionalized compounds, dehalogenated compounds, oxidized compounds, reduced compounds, isomers, and sensitized compounds. Solar energy is a renewable resource that can be harvested from the sun and this light energy can be changed into chemical energy with the help of photocatalysts. During this green approach, electron-hole pairs are generated in photocatalysts in order to begin reactions by using solar light. It has been highlighted in this article that there have been impressive developments in the use of light, mainly the solar light, to promote important organic reactions, which would otherwise be unattainable under thermal conditions.

摘要

在过去几年中,光催化方法作为低成本、环境友好且可持续的技术展现出了巨大潜力。在光化学发展过程中,使用了多种光源,包括阳光、紧凑型荧光灯、激光,甚至发光二极管。作为制备各种有机化合物的一部分,采用了光化学方法,例如形成环、芳基化化合物、环加成、功能化化合物、脱卤化合物、氧化化合物、还原化合物、异构体和敏化化合物。太阳能是一种可再生资源,可以从太阳获取,并且这种光能在光催化剂的帮助下可以转化为化学能。在这种绿色方法中,光催化剂中会产生电子 - 空穴对,以便利用太阳光引发反应。本文强调,在利用光,主要是太阳光来促进重要有机反应方面已经取得了令人瞩目的进展,而这些反应在热条件下原本是无法实现的。

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本文引用的文献

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Preparation of metal-free BP/CN photocatalyst with enhanced ability for photocatalytic tetracycline degradation.制备具有增强光催化四环素降解能力的无金属 BP/CN 光催化剂。
Chemosphere. 2022 Mar;290:133317. doi: 10.1016/j.chemosphere.2021.133317. Epub 2021 Dec 15.
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Mild olefin formation bio-inspired vitamin B photocatalysis.温和的烯烃形成:受生物启发的维生素B光催化作用
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构建 MoO3 纳米颗粒/g-C3N4 纳米片 0D/2D 异质结光催化剂以增强抗生素污染物的光催化降解。
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Disorder Engineering in Monolayer Nanosheets Enabling Photothermic Catalysis for Full Solar Spectrum (250-2500 nm) Harvesting.单层纳米片中的无序工程实现用于全太阳光谱(250 - 2500 nm)捕获的光热催化
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Photochemical Stereocontrol Using Tandem Photoredox-Chiral Lewis Acid Catalysis.光化学立体控制的串联光氧化还原-手性路易斯酸催化。
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Photoredox Catalysis in Organic Chemistry.光氧化还原催化在有机化学中的应用。
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