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不同温度退火的ZnO薄膜中的入射光子截止能量、光学线性方程和电子-声子相互作用。

The incident photons cut-off energy, the optical linear equations and the electron phonon interactions in ZnO thin films annealed at different temperatures.

作者信息

Dalouji Vali

机构信息

Department of Physics, Faculty of science, Malayer University, Malayer, Iran.

出版信息

Heliyon. 2024 Sep 7;10(18):e37509. doi: 10.1016/j.heliyon.2024.e37509. eCollection 2024 Sep 30.

Abstract

The using RF-magnetron sputtering, the ZnO thin films were deposited on glass substrates at room temperature. Then using an electrical furnace in the presence of argon gas, they were annealed at different temperatures (400-600 °C). It was found that with taking  = 4,  = 2,  = 8 for ZnO films for covalently bonded crystalline and amorphous chalcogenides, the constant β has values of about 0.37 ± 0.04 and for halides and most oxides that have ionic structure the constant β has values of about 0.26 ± 0.04 eV. It can be seen that with increasing annealing temperature absorption edge these films have a shifting behavior towards larger wavelength. Due to shifting behavior of defects distribution of atoms into films, the values of the cut-off energy, E cut-off and the λ cut-off of these films were about 3.48 eV and 355 nm, respectively. The ZnO films annealed at 500 °C specially above 3 eV have maximum value of optical density. The different linears fitting of ln (⍺) for films were obtained as y = Ex + F where 10<E < 12.5 and 14<F < 16. The ZnO films annealed at 600 °C have minimum value of electron phonon interaction (E) in a bout of 0.858 eV. The optical band gap and disordering energy plots of these films can be fitted by linear relationship and   0.0989-0.148 . We found that as deposited ZnO films have minimum value of steepness parameter in about of 30.93 10 .

摘要

采用射频磁控溅射法,在室温下将ZnO薄膜沉积在玻璃基板上。然后在氩气氛围下使用电炉,将它们在不同温度(400 - 600°C)下退火。结果发现,对于共价键合的晶体和非晶硫属化物的ZnO薄膜,取 = 4, = 2, = 8时,常数β的值约为0.37±0.04;对于具有离子结构的卤化物和大多数氧化物,常数β的值约为0.26±0.04 eV。可以看出,随着退火温度的升高,这些薄膜的吸收边向更大波长方向移动。由于薄膜中原子缺陷分布的移动行为,这些薄膜的截止能量E截止和λ截止值分别约为3.48 eV和355 nm。在500°C退火的ZnO薄膜,特别是在3 eV以上,具有最大的光密度值。薄膜的ln(⍺)的不同线性拟合结果为y = Ex + F,其中10 < E < 12.5且14 < F < 16。在600°C退火的ZnO薄膜的电子声子相互作用(E)的最小值约为0.858 eV。这些薄膜的光学带隙和无序能量图可以用线性关系 和 0.0989 - 0.148拟合。我们发现,沉积态的ZnO薄膜的陡度参数最小值约为30.93×10 。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e9e2/11416522/8d4adfa45470/gr1.jpg

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