Sun Xiaojun, Lin Xiao, Luo Yang, Yu Dunbo, Yan Wenlong, Zhang Hongbin, Wang Zilong, Zhang Chaofan, Guo Jiyuan, Zhang Wendi, Gao Weiguo, Huang Shan
National Engineering Research Center for Rare Earth, Grirem Hi-Tech Co., Langfang 065201, China.
Grirem (Rongcheng) Co., Ltd., Weihai 264306, China.
Materials (Basel). 2024 Sep 20;17(18):4626. doi: 10.3390/ma17184626.
The rheological behavior and printing characteristics of the screen-printing slurry for Nd-Fe-B grain boundary diffusion are key factors that determine the quality of printing and magnetic performance. However, few studies have focused on the organic medium, a crucial material for slurry. In this paper, the rheology, thixotropy, and thermal decomposition behavior of the organic vehicle in Nd-Fe-B screen printing slurry were studied. The results show that the organic vehicle formed by terpineol and polyvinyl butyral (PVB) exhibits typical non-Newtonian fluid characteristics, with excellent rheology and thixotropy, ensuring that the slurry prepared from it has excellent static stability and printing consistency. Additionally, the carbon residue of the organic vehicle formed by terpineol and PVB is less than 0.1% at 900 °C, avoiding excessive carbon entering the magnet during the diffusion process. Moreover, studying the rheology and thixotropy of the organic vehicle through a rheometer can quickly screen the slurry system. This work provides valuable guidance for designing an organic vehicle for screen-printing slurry for Nd-Fe-B grain boundary diffusion in future research.
钕铁硼晶界扩散丝网印刷浆料的流变行为和印刷特性是决定印刷质量和磁性能的关键因素。然而,很少有研究关注浆料的关键材料——有机介质。本文研究了钕铁硼丝网印刷浆料中有机载体的流变学、触变性和热分解行为。结果表明,由松油醇和聚乙烯醇缩丁醛(PVB)形成的有机载体表现出典型的非牛顿流体特性,具有优异的流变学和触变性,确保由其制备的浆料具有优异的静态稳定性和印刷一致性。此外,由松油醇和PVB形成的有机载体在900℃时的残碳量小于0.1%,避免了在扩散过程中过多的碳进入磁体。而且,通过流变仪研究有机载体的流变学和触变性可以快速筛选浆料体系。这项工作为未来研究中设计用于钕铁硼晶界扩散丝网印刷浆料的有机载体提供了有价值的指导。