Sayago Uriel Fernando Carreño, Ballesteros Vladimir Ballesteros, Aguilar Angelica María Lozano
Faculty of Engineering and Basic Sciences, Fundación Universitaria los Libertadores, Bogotá 111221, Colombia.
Polymers (Basel). 2024 Sep 14;16(18):2605. doi: 10.3390/polym16182605.
The search for adsorbents that are non-toxic and low cost with a high adsorption capacity and excellent recyclability is a priority to determine the way to reduce the serious environmental impacts caused by the discharge of effluents loaded with heavy metals. Bacterial cellulose (BC) biomass has functional groups such as hydroxyl and carbonyl groups that play a crucial role in making this cellulose so efficient at removing contaminants present in water through cation exchange. This research aims to develop an experimental process for the adsorption, elution, and reuse of bacterial cellulose biomass in treating water contaminated with Cr (VI). SEM images and the kinetics behavior were analyzed with pseudo-first- and pseudo-second-order models together with isothermal analysis after each elution and reuse process. The adsorption behavior was in excellent agreement with the Langmuir model along with its elution and reuse; the adsorption capacity was up to 225 mg/g, adding all the elution processes. This study presents a novel approach to the preparation of biomass capable of retaining Cr (VI) with an excellent adsorption capacity and high stability. This method eliminates the need for chemical agents, which would otherwise be difficult to implement due to their costs. The viability of this approach for the field of industrial wastewater treatment is demonstrated.
寻找无毒、低成本、具有高吸附容量和出色可回收性的吸附剂,是确定减少含重金属废水排放所造成严重环境影响方法的首要任务。细菌纤维素(BC)生物质具有羟基和羰基等官能团,这些官能团在使这种纤维素通过阳离子交换有效去除水中污染物方面起着关键作用。本研究旨在开发一种用于细菌纤维素生物质吸附、洗脱和再利用的实验工艺,以处理受六价铬污染的水。在每次洗脱和再利用过程后,用准一级和准二级模型以及等温分析对扫描电子显微镜(SEM)图像和动力学行为进行了分析。吸附行为与其洗脱和再利用过程与朗缪尔模型高度吻合;加上所有洗脱过程,吸附容量高达225 mg/g。本研究提出了一种制备能够保留六价铬、具有出色吸附容量和高稳定性生物质的新方法。该方法无需化学药剂,否则由于成本原因将难以实施。证明了这种方法在工业废水处理领域的可行性。