Wang Yuanwu, Tang Qiheng, Chen Xueqi, Luo Xiaoxi, Zhang Fenghao, Zhou Guanwu, Zhang Jie, Zhang Lei, Meng Yuan, Ren Yiping, Chang Liang, Guo Wenjing
Research Institute of Wood Industry, Chinese Academy of Forestry, No.1 Dongxiaofu, Haidian District, Beijing 10091, China.
Polymers (Basel). 2024 Sep 18;16(18):2637. doi: 10.3390/polym16182637.
Plywood is lightweight, strong, and durable, making it a widely used material in building decoration and furniture areas. In this study, formaldehyde-free, high-strength plywood was prepared through the incorporation of carbon fiber fabrics (CFFs) as reinforcement layers and their bonding with maleic anhydride polyethylene (MAPE) films. Various tests were performed to assess the impact of the carbon fiber fabric positioning on the physical and mechanical properties of plywood, including tensile shear strength, flexural strength, water absorption, thickness swelling, and electro-thermal properties. The results revealed that the plywood with CFFs exhibited significantly higher mechanical properties than plywood without CFFs. Particularly, the addition of CFFs increased the tensile strength of the plywood by nearly 54.43%, regardless of the CFFs' position. The symmetric placement of CFFs near the bottom and upper layers of the plywood resulted in a maximum modulus of rupture of 85.6 MPa. These findings were validated by numerical simulations. Scanning electron microscopy analysis of the plywood microstructures revealed that MAPE penetrated both the vessels and xylem of the wood veneers and the pores of the CFFs, thereby improving the mechanical properties of the plywood. Plywood reinforced with CFFs exhibited increased water absorption and thickness swelling after immersion. Additionally, the placement of CFFs influenced the electro-thermal properties of the plywood. Plywood with CFFs positioned near the bottom and upper surfaces exhibited superior thermal conductivity. Overall, this study presents a feasible method for developing high-performance, formaldehyde-free plywood and sustainable wood-based structural materials with potential applications in geothermal flooring.
胶合板重量轻、强度高且耐用,使其成为建筑装饰和家具领域广泛使用的材料。在本研究中,通过加入碳纤维织物(CFFs)作为增强层并使其与马来酸酐聚乙烯(MAPE)薄膜粘结,制备了无甲醛高强度胶合板。进行了各种测试,以评估碳纤维织物的位置对胶合板物理和机械性能的影响,包括拉伸剪切强度、弯曲强度、吸水性、厚度膨胀率和电热性能。结果表明,含有CFFs的胶合板的机械性能明显高于不含CFFs的胶合板。特别是,无论CFFs的位置如何,添加CFFs使胶合板的拉伸强度提高了近54.43%。CFFs在胶合板底层和上层附近对称放置时,最大断裂模量为85.6 MPa。这些发现通过数值模拟得到了验证。对胶合板微观结构的扫描电子显微镜分析表明,MAPE渗透到木单板的导管和木质部以及CFFs的孔隙中,从而提高了胶合板的机械性能。用CFFs增强的胶合板在浸泡后吸水性和厚度膨胀率增加。此外,CFFs的位置影响了胶合板的电热性能。CFFs位于底部和上表面附近的胶合板表现出优异的热导率。总体而言,本研究提出了一种开发高性能、无甲醛胶合板以及具有在地热地板中潜在应用的可持续木质结构材料的可行方法。