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用镧系掺杂上转换纳米杂化物实现近红外触发的α-萜品烯光氧化反应

NIR-triggered photooxygenation of α-terpinene with upconversion nanohybrids.

作者信息

Francés-Soriano Laura, Bellezza Delia, Ferrera-González Juan, González-Béjar María, Pérez-Prieto Julia

机构信息

Instituto de Ciencia Molecular (ICMol), Departamento de Química Orgánica, Universitat de València Calle Catedrático José Beltrán 2 Paterna Valencia 46980 Spain

出版信息

Nanoscale Adv. 2024 Sep 11;6(23):5889-96. doi: 10.1039/d4na00528g.

DOI:10.1039/d4na00528g
PMID:39355838
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11440474/
Abstract

Upconversion nanohybrids (UCNHs) consisting of rose bengal (RB) and upconversion nanoparticles (UCNPs) are able to promote terpinene oxidation upon near-infrared irradiation. The photophysical events occurring upon NIR-irradiation of the UCNH correlate well with the synthetic protocol used to prepare the UCNHs (RB loading and aggregation). These results highlight the importance of the optimization of UCNH composition for the photocatalysis outcome.

摘要

由孟加拉玫瑰红(RB)和上转换纳米颗粒(UCNP)组成的上转换纳米杂化物(UCNH)在近红外照射下能够促进萜品烯氧化。UCNH近红外照射时发生的光物理事件与用于制备UCNH的合成方案(RB负载和聚集)密切相关。这些结果突出了优化UCNH组成对光催化结果的重要性。

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本文引用的文献

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Second Generation of Near-Infrared Cyanine-Based Photocatalysts for Faster Organic Transformations.用于更快有机转化的第二代基于近红外花青的光催化剂。
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Squaraines as near-infrared photocatalysts for organic reactions.
方酸作为近红外光催化剂用于有机反应。
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Cancer-cell-biomimetic Upconversion nanoparticles combining chemo-photodynamic therapy and CD73 blockade for metastatic triple-negative breast cancer.基于癌细胞仿生的上转换纳米粒子联合化学-光动力疗法和 CD73 阻断治疗转移性三阴性乳腺癌。
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