Pellizzari E D, Moseley M A, Cooper S D
J Chromatogr. 1985 Nov 15;334(3):277-314. doi: 10.1016/s0021-9673(00)80273-3.
Analytical advances in the detection, identification and quantification of polychlorinated biphenyl isomers (PCBs) are reviewed. High-resolution gas chromatography, with specific reference to capillary column development and support "phases", methodologies, detector systems and the comparative advantages and limitations of each combination, is covered. Problems associated with instrument calibration, general non-availability of primary PCB standards and the use of secondary standards are discussed. Typical applications of these newer methods to environmental, biological and process stream samples are presented.
本文综述了多氯联苯异构体（PCBs）检测、鉴定和定量分析方面的进展。重点介绍了高分辨率气相色谱法，包括毛细管柱的发展、载体“相”、方法、检测系统以及每种组合的相对优势和局限性。讨论了与仪器校准、多氯联苯一级标准品普遍不可用以及二级标准品使用相关的问题。还介绍了这些新方法在环境、生物和工艺流样品中的典型应用。
