• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于定向纳米线的混合热电材料的制备与表征

Fabrication and characterization of hybrid thermoelectric materials based on aligned nanowires.

作者信息

Lee Min-Jeong, Kim Chae Yoon, Lim Jae-Hong

机构信息

Department of Material Science and Engineering, Gachon University, Seongnam, Republic of Korea.

出版信息

Front Chem. 2024 Sep 26;12:1407129. doi: 10.3389/fchem.2024.1407129. eCollection 2024.

DOI:10.3389/fchem.2024.1407129
PMID:39391833
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11464297/
Abstract

This study introduces the synthesis of a hybrid thermoelectric material with enhanced conductivity and a high Seebeck coefficient, leveraging the properties of Te nanowires (NWs) and the conductive polymer PEDOT:PSS. Te NWs were synthesized using the galvanic displacement reaction. To further enhance conductivity, Ag-Te NWs were synthesized under optimized conditions via the Ag topotactic reaction, achieving desired results within 7 min using ethylene glycol and AgNO. This hybrid material exhibited an electrical conductivity of 463 S/cm, a Seebeck coefficient of 69.5 μV/K at 300 K, and a power factor of 260 μW/mK. These metrics surpassed those of conventional Te/PEDOT:PSS hybrids by a factor of 3.6, highlighting the superior performance of our approach. This study represents a significant advancement in thermoelectric materials, improving both conductivity and efficiency.

摘要

本研究利用碲纳米线（NWs）和导电聚合物聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐（PEDOT:PSS）的特性，介绍了一种具有增强导电性和高塞贝克系数的混合热电材料的合成方法。碲纳米线通过电置换反应合成。为了进一步提高导电性，通过银拓扑化学反应在优化条件下合成了银-碲纳米线，使用乙二醇和硝酸银在7分钟内达到了预期效果。这种混合材料在300K时表现出463 S/cm的电导率、69.5 μV/K的塞贝克系数和260 μW/mK的功率因数。这些指标比传统的碲/聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐混合材料高出3.6倍，突出了我们方法的卓越性能。这项研究代表了热电材料的重大进展，提高了导电性和效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/2543b244f58b/fchem-12-1407129-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/39af0fa376c1/fchem-12-1407129-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/a96797a6685f/fchem-12-1407129-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/35f35f04ca69/fchem-12-1407129-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/af785145fb4d/fchem-12-1407129-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/c50e37e5acde/fchem-12-1407129-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/278d607bbad1/fchem-12-1407129-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/89b2e61cad85/fchem-12-1407129-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/cb67c0a52751/fchem-12-1407129-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/2543b244f58b/fchem-12-1407129-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/39af0fa376c1/fchem-12-1407129-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/a96797a6685f/fchem-12-1407129-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/35f35f04ca69/fchem-12-1407129-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/af785145fb4d/fchem-12-1407129-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/c50e37e5acde/fchem-12-1407129-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/278d607bbad1/fchem-12-1407129-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/89b2e61cad85/fchem-12-1407129-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/cb67c0a52751/fchem-12-1407129-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64c/11464297/2543b244f58b/fchem-12-1407129-g009.jpg

相似文献

1
Fabrication and characterization of hybrid thermoelectric materials based on aligned nanowires.基于定向纳米线的混合热电材料的制备与表征
Front Chem. 2024 Sep 26;12:1407129. doi: 10.3389/fchem.2024.1407129. eCollection 2024.
2
Enhanced thermoelectric performance of PEDOT:PSS flexible bulky papers by treatment with secondary dopants.通过二次掺杂剂处理提高PEDOT:PSS柔性厚纸的热电性能。
ACS Appl Mater Interfaces. 2015 Jan 14;7(1):94-100. doi: 10.1021/am507032e. Epub 2014 Dec 29.
3
Solution synthesis of telluride-based nano-barbell structures coated with PEDOT:PSS for spray-printed thermoelectric generators.基于碲化物的纳米棒状结构的溶液合成，其表面涂有 PEDOT:PSS，用于喷涂式热电发电机。
Nanoscale. 2016 Jun 7;8(21):10885-90. doi: 10.1039/c5nr07032e. Epub 2016 Jan 14.
4
Properties of PEDOT nanowire/Te nanowire nanocomposites and fabrication of a flexible thermoelectric generator.聚（3,4-乙撑二氧噻吩）纳米线/碲纳米线纳米复合材料的性质及柔性热电发电机的制备
RSC Adv. 2020 Sep 14;10(56):33965-33971. doi: 10.1039/d0ra02223c. eCollection 2020 Sep 10.
5
Improved Thermoelectric Properties and Environmental Stability of Conducting PEDOT:PSS Films Post-treated With Imidazolium Ionic Liquids.咪唑鎓离子液体后处理的导电聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐（PEDOT:PSS）薄膜的热电性能和环境稳定性得到改善
Front Chem. 2020 Jan 8;7:870. doi: 10.3389/fchem.2019.00870. eCollection 2019.
6
Preparation and Characterization of Thermoelectric PEDOT/Te Nanorod Array Composite Films.热电PEDOT/Te纳米棒阵列复合薄膜的制备与表征
Materials (Basel). 2021 Dec 25;15(1):148. doi: 10.3390/ma15010148.
7
Enhancement of Thermoelectric Properties of PEDOT:PSS and Tellurium-PEDOT:PSS Hybrid Composites by Simple Chemical Treatment.通过简单化学处理提高聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐（PEDOT:PSS）和碲-聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐（Tellurium-PEDOT:PSS）杂化复合材料的热电性能
Sci Rep. 2016 Jan 5;6:18805. doi: 10.1038/srep18805.
8
Enhanced Thermoelectric Properties of Coated Vanadium Oxynitride Nanoparticles/PEDOT:PSS Hybrid Films.包覆的氮氧化钒纳米颗粒/PEDOT:PSS混合薄膜的增强热电性能
ACS Appl Mater Interfaces. 2023 Feb 22;15(7):9953-9961. doi: 10.1021/acsami.2c19809. Epub 2023 Feb 13.
9
Fabrication of PEDOT: PSS-PVP Nanofiber-Embedded SbTe Thermoelectric Films by Multi-Step Coating and Their Improved Thermoelectric Properties.通过多步涂层制备聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐-聚乙烯吡咯烷酮纳米纤维嵌入的SbTe热电薄膜及其改善的热电性能
Materials (Basel). 2020 Jun 24;13(12):2835. doi: 10.3390/ma13122835.
10
Self-Assembled Three-Dimensional BiTe Nanowire-PEDOT:PSS Hybrid Nanofilm Network for Ubiquitous Thermoelectrics.用于无处不在的热电学的自组装三维 BiTe 纳米线-PEDOT:PSS 杂化纳米纤维网络
ACS Appl Mater Interfaces. 2019 Feb 13;11(6):6624-6633. doi: 10.1021/acsami.8b19767. Epub 2019 Feb 5.

本文引用的文献

1
Advanced Thermoelectric Design: From Materials and Structures to Devices.先进热电设计：从材料与结构到器件
Chem Rev. 2020 Aug 12;120(15):7399-7515. doi: 10.1021/acs.chemrev.0c00026. Epub 2020 Jul 2.
2
Thermoelectrics of Nanowires.纳米线的热电学
Chem Rev. 2019 Aug 14;119(15):9260-9302. doi: 10.1021/acs.chemrev.8b00627. Epub 2019 Mar 18.
3
High Thermoelectric Performance in Two-Dimensional Tellurium: An Ab Initio Study.二维碲中的高热电性能：从头算研究。
ACS Appl Mater Interfaces. 2018 Nov 28;10(47):40702-40709. doi: 10.1021/acsami.8b11836. Epub 2018 Nov 14.
4
Two-Channel Thermal Transport in Ordered-Disordered Superionic AgTe and Its Traditionally Contradictory Enhancement by Nanotwin Boundary.有序-无序超离子AgTe中的双通道热输运及其由纳米孪晶界引起的传统矛盾增强
J Phys Chem Lett. 2018 Oct 4;9(19):5704-5709. doi: 10.1021/acs.jpclett.8b02542. Epub 2018 Sep 17.
5
Tellurium as a high-performance elemental thermoelectric.碲作为一种高性能元素热电材料。
Nat Commun. 2016 Jan 11;7:10287. doi: 10.1038/ncomms10287.
6
Three-dimensional hierarchical Te-Si nanostructures.三维分级碲-硅纳米结构
Nanoscale. 2014 Oct 21;6(20):11697-702. doi: 10.1039/c4nr02469a. Epub 2014 Jul 3.
7
Low-dimensional Te-based nanostructures.基于 Te 的低维纳米结构。
Adv Mater. 2013 Jul 26;25(28):3915-21. doi: 10.1002/adma.201301128. Epub 2013 May 27.
8
Engineered doping of organic semiconductors for enhanced thermoelectric efficiency.有机半导体的工程掺杂以提高热电效率。
Nat Mater. 2013 Aug;12(8):719-23. doi: 10.1038/nmat3635. Epub 2013 May 5.
9
Extremely high electron mobility in a phonon-glass semimetal.在声子玻璃半导体中具有极高的电子迁移率。
Nat Mater. 2013 Jun;12(6):512-7. doi: 10.1038/nmat3621. Epub 2013 Apr 21.
10
Branched tellurium hollow nanofibers by galvanic displacement reaction and their sensing performance toward nitrogen dioxide.通过电置换反应制备的分支碲中空纳米纤维及其对二氧化氮的传感性能。
Nanoscale. 2013 Apr 7;5(7):3058-62. doi: 10.1039/c3nr00060e.