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识别中国胶州湾北部沿海地区的地下水特征及控制因素:多元统计、同位素分析和现场实证调查的综合方法

Identifying groundwater characteristics and controlling factors in Jiaozhou Bay's northern coastal region, China: a combined approach of multivariate statistics, isotope analysis, and field empirical investigations.

作者信息

Ji Dong, Ma Jian, Xue Junzhuo, Wu Xinghui, Wang Zeyong, Wei Shuai

机构信息

College of Civil Engineering and Transport, Weifang University, Weifang, 261061, China.

Qingdao Surveying and Mapping Institute, Qingdao, 266032, China.

出版信息

Sci Rep. 2024 Oct 11;14(1):23856. doi: 10.1038/s41598-024-75425-x.

Abstract

Explicit identification of hydrochemical processes and their controlling factors within groundwater systems is critical for the sustainable utilization of water resources in coastal urban areas. This study was undertaken in the North Coastal Region of Jiaozhou Bay (NCRJB), located in the eastern part of Shandong Province, China, an area grappling with significant issues of groundwater quality degradation and water scarcity. A total of 105 groundwater samples and 34 surface water samples, collected from 2020 to 2024, were analyzed and studied using various hydrogeological tools, multivariate statistical analyses, and water quality assessment methods. These include the Piper diagram, hydrochemical facies evolution diagram (HFE-D), Principal Components Analysis (PCA), correlation analysis, stable isotope analysis, Water Quality Index (WQI), and USSL diagrams. The results indicated that all surface water and pore groundwater samples were categorized as Na-Cl type, exhibiting high Total Dissolved Solids (TDS) and Electrical Conductivity (EC) values, characteristics that render them poor to unsuitable for drinking and irrigation purposes. The fracture groundwater is predominantly of the Ca-Na-Cl mixed type, with average suitability for irrigation and a limited proportion (22.5%) deemed suitable for drinking. Seawater intrusion, primarily through the surface water system, and the impact of human activities were identified as the predominant controlling factors con-tributing to the degradation of the local groundwater environment. Field empirical investigations further validated the results derived from hydrogeological assessments, multivariate statistical analyses, and isotopic approaches. The long-term shifts in hydrochemical properties, along with the latent threat of seawater intrusion, exhibit an upward trend during the dry season and show a certain degree of mitigation during the wet season. This study highlights that field investigations, in conjunction with hydrochemical tools, multivariate statistical analyses, and stable isotope analysis, can successfully furnish reliable insights into the predominant mechanisms governing regional groundwater evolution within the context of long-term and intricate envi-ronmental settings.

摘要

明确识别地下水系统中的水化学过程及其控制因素,对于沿海城市地区水资源的可持续利用至关重要。本研究是在胶州湾北部沿海地区(NCRJB)开展的,该地区位于中国山东省东部,正面临着地下水质量退化和水资源短缺等重大问题。2020年至2024年期间共采集了105份地下水样本和34份地表水样本,并运用多种水文地质工具、多元统计分析方法和水质评估方法进行了分析和研究。这些方法包括派珀图、水化学相演化图(HFE-D)、主成分分析(PCA)、相关性分析、稳定同位素分析、水质指数(WQI)和USSL图。结果表明,所有地表水和孔隙地下水样本均归类为Na-Cl型,总溶解固体(TDS)和电导率(EC)值较高,这些特征使其不适宜饮用和灌溉。裂隙地下水主要为Ca-Na-Cl混合型,平均适宜灌溉,仅有22.5%的比例被认为适宜饮用。海水入侵主要通过地表水系统以及人类活动的影响,被确定为导致当地地下水环境退化的主要控制因素。实地经验调查进一步验证了水文地质评估、多元统计分析和同位素方法得出的结果。水化学性质的长期变化以及海水入侵的潜在威胁,在旱季呈上升趋势,在雨季则有所缓解。本研究强调,实地调查结合水化学工具、多元统计分析和稳定同位素分析,能够成功地为长期复杂环境背景下区域地下水演化的主要机制提供可靠的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcbd/11470051/fab583ac8c7b/41598_2024_75425_Fig1_HTML.jpg

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