Deep Eutectic Solvent as a New Zeta Potential Altering Chemical for Sand Agglomeration.

Fines migration can cause various issues, such as plugging of the sand screen and damage to tubings. There are two chemical sand control methods: consolidation and agglomeration. Consolidation works by injection of a solvent into the formation to harden over time and hold the sand in place, while agglomeration works by altering chemical properties of the sand surface to attract and clump up sand. Various chemicals have been used for research in sand control. Some chemicals for consolidation, mostly resins, have been effective in consolidating sand but may cause permeability impairment, which will reduce production. Some chemicals for agglomeration such as a polymer with amines have been less effective or are nonbiodegradable. In this work, a novel deep eutectic solvent (DES) and ionic polymer combination as a fines stabilizer is formulated in-house and tested through extensive experimental study. The development of chemicals is based on agglomeration principles which determine the range of zeta potential reduction that can be achieved to destabilize, coagulate, and flocculate the fine particles together with different combinations of DESs and ionic polymers tested systematically using the design of experiment (DoE) method. The chemicals are then tested for compatibility with reservoir fluids in the jar test. The optimized formulation is characterized by thermogravimetric analysis (TGA) for limit of temperature degradation and laser particle size analysis (LPSA) for the extent of particle size. The novelty of this work is the development of a greener and more cost-saving in-house DES and ionic polymer combination as a fines stabilizer chemical, which is effective for both injection or production wells after stimulation or enhanced oil recovery (EOR) treatments. Due to the tunable nature of the DES, the formulated chemical can be tailored for various reservoir conditions to cater to specific requirements.