Impact of Wettability on CO Dynamic Dissolution in Three-Dimensional Porous Media: Pore-Scale Simulation Using the Lattice Boltzmann Method.

Understanding the dissolution behavior of supercritical CO (scCO) in porous media is crucial for efficient CO storage. However, the precise modeling of dynamic dissolution behavior at this pore scale remains a huge challenge, and the impact of wettability on this process still needs to be clarified. In this study, the influence of rock wettability on CO dynamic dissolution in the three-dimensional porous media is investigated using the lattice Boltzmann method (LBM). The LBM is coupled with scCO-water two-phase flow, solute transport, and heterogeneous and homogeneous reactions. The size, number, and dissolution pattern of scCO bubbles during the dissolution process are observed under strongly water-wet, weakly water-wet, intermediate-wet, and mixed-wet conditions. The CO(aq) concentration and pH are investigated, followed by a quantitative investigation of the impact of wettability on the specific interface area and the mass transfer coefficient. An empirical relationship between the specific interface area and scCO saturation is established. The findings reveal that under weakly water-wet and intermediate-wet conditions, the sizes of scCO clusters and monomers are small and mostly distributed at the dead end of the pores. In contrast, under strongly water-wet and mixed-wet conditions, the clusters are larger and interconnected, and distributed in the center of the pore. This results in a greater scCO-water interface area, consequently enhancing the dissolution rate. Furthermore, a strong linear correlation is observed between scCO saturation and specific interface area. It is noted that as the hydrophilicity of the rock increases, the mass transfer coefficient initially rises and then declines.