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可再生资源作为获取类氧化石墨烯结构的有前景材料。

Renewable Resources as Promising Materials for Obtaining Graphene Oxide-like Structures.

作者信息

Kuanyshbekov Tilek, Akatan Kydyrmolla, Guseinov Nazim, Nemkaeva Renata, Kurbanova Bayan, Tolepov Zhandos, Tulegenova Malika, Kabdrakhmanova Sana, Zhilkashinova Almira

机构信息

National Scientific Laboratory of Collective Use, Sarsen Amanzholov East Kazakhstan University, 55 Kazakhstan Str., Ust-Kamenogorsk 070002, Kazakhstan.

Kaz Graphene, 63 Zapadnyi Str., Ust-Kamenogorsk 070011, Kazakhstan.

出版信息

Nanomaterials (Basel). 2024 Oct 1;14(19):1588. doi: 10.3390/nano14191588.

Abstract

Currently, one of the topical directions in the field of production and application of graphene-like nanostructures is the use of renewable natural raw materials, which have unlimited resources for an economically efficient large-scale yield of a product with environmental safety. In this regard, we present the production of graphene oxide (GO) from a renewable natural raw material of plant biomass, birch activated carbon (BAC), and a comparison of the obtained physicochemical, mechanical, and electrical properties of birch activated carbon-graphene oxide (BAC-GO) and graphite-graphene oxide (G-GO) synthesized from the initial materials, BAC and graphite (G). Results obtained from this study confirm the successful oxidation of BAC, which correlates well with the physical-chemical dates of the G-GO and BAC-GO samples. Change in data after the oxidation of graphite and BAC was facilitated by the structure of the starting materials and, presumably, the location and content of functional oxygen-containing groups in the G-GO and BAC-GO chains. Based on the results, the application of a cost-effective, eco-friendly colloidal solution of nanodispersed BAC-GO from a plant biomass-based high-quality resource for producing large-scale nanostructured graphene is validated which has potential applicability in nanoelectronics, medicine, and other fields.

摘要

目前,类石墨烯纳米结构的生产和应用领域的热门方向之一是使用可再生天然原料,这些原料具有无限资源,可经济高效地大规模生产具有环境安全性的产品。在这方面,我们展示了从植物生物质的可再生天然原料桦木活性炭(BAC)制备氧化石墨烯(GO),并比较了由初始原料BAC和石墨(G)合成的桦木活性炭-氧化石墨烯(BAC-GO)和石墨-氧化石墨烯(G-GO)所获得的物理化学、机械和电学性质。本研究获得的结果证实了BAC的成功氧化,这与G-GO和BAC-GO样品的物理化学数据高度相关。石墨和BAC氧化后数据的变化受起始材料的结构以及大概G-GO和BAC-GO链中含氧官能团的位置和含量的影响。基于这些结果,验证了从基于植物生物质的优质资源制备具有成本效益、环境友好的纳米分散BAC-GO胶体溶液用于大规模生产纳米结构石墨烯的应用,其在纳米电子学、医学和其他领域具有潜在适用性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d0/11478307/5500594316b3/nanomaterials-14-01588-g001.jpg

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