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基于石墨烯和MXene的复合材料在气体传感方面的比较综述

A Comparative Review of Graphene and MXene-Based Composites towards Gas Sensing.

作者信息

Vaishag Pushpalatha Vijayakumar, Noh Jin-Seo

机构信息

Department of Physics, Gachon University, 1342 Seongnamdaero, Sujeong-gu, Seongnam-si 13120, Gyeonggi-do, Republic of Korea.

出版信息

Molecules. 2024 Sep 25;29(19):4558. doi: 10.3390/molecules29194558.

Abstract

Graphene and MXenes have emerged as promising materials for gas sensing applications due to their unique properties and superior performance. This review focuses on the fabrication techniques, applications, and sensing mechanisms of graphene and MXene-based composites in gas sensing. Gas sensors are crucial in various fields, including healthcare, environmental monitoring, and industrial safety, for detecting and monitoring gases such as hydrogen sulfide (HS), nitrogen dioxide (NO), and ammonia (NH). Conventional metal oxides like tin oxide (SnO) and zinc oxide (ZnO) have been widely used, but graphene and MXenes offer enhanced sensitivity, selectivity, and response times. Graphene-based sensors can detect low concentrations of gases like HS and NH, while functionalization can improve their gas-specific selectivity. MXenes, a new class of two-dimensional materials, exhibit high electrical conductivity and tunable surface chemistry, making them suitable for selective and sensitive detection of various gases, including VOCs and humidity. Other materials, such as metal-organic frameworks (MOFs) and conducting polymers, have also shown potential in gas sensing applications, which may be doped into graphene and MXene layers to improve the sensitivity of the sensors.

摘要

由于其独特的性能和卓越的表现,石墨烯和MXenes已成为气体传感应用中颇具前景的材料。本综述聚焦于基于石墨烯和MXene的复合材料在气体传感中的制备技术、应用及传感机制。气体传感器在包括医疗保健、环境监测和工业安全等各个领域对于检测和监测诸如硫化氢(HS)、二氧化氮(NO)和氨(NH)等气体至关重要。传统的金属氧化物如氧化锡(SnO)和氧化锌(ZnO)已被广泛使用,但石墨烯和MXenes具有更高的灵敏度、选择性和响应时间。基于石墨烯的传感器能够检测低浓度的气体如HS和NH,而功能化可以提高其对特定气体的选择性。MXenes作为一类新型的二维材料,具有高电导率和可调节的表面化学性质,使其适用于对包括挥发性有机化合物(VOCs)和湿度在内的各种气体进行选择性和灵敏检测。其他材料,如金属有机框架(MOFs)和导电聚合物,在气体传感应用中也显示出潜力,它们可以掺杂到石墨烯和MXene层中以提高传感器的灵敏度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e861/11478074/a870662a4551/molecules-29-04558-g001.jpg

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