Avitabile Marika, Mirpoor Seyedeh Fatemeh, Esposito Sefora, Merola Giusi, Mariniello Loredana, Patanè Giuseppe Tancredi, Barreca Davide, Giosafatto Concetta Valeria Lucia
Department of Chemical Sciences, University of Naples Federico II, 80126 Naples, Italy.
Department of Food and Nutritional Sciences, University of Reading, P.O. Box 226, Whiteknights, Reading RG6 6AP, UK.
Polymers (Basel). 2024 Sep 24;16(19):2693. doi: 10.3390/polym16192693.
The exploration of natural resources in bioplastics has advanced the development of bio-based materials. Utilizing the casting, chitosan (CH)-based films were manufactured with different glycerol (GLY) percentages (from 0 to 50% / of CH) and anthocyanin-enriched fractions (from 0 to 5% of / CH) of acidified ethanol extract of flowers (CCE). is an ornamental plant known for its bioactive compounds endowed with health benefits. The hydrocolloid films showed promising mechanical properties. The 30% GLY + 5% CCE film achieved an elongation at break of 57.4%, comparable to the 50% GLY film while possessing enhanced tensile strength and Young's modulus. The CCE, rich in antioxidants, acted as a plasticizer, improving films' flexibility and manageability. The films exhibit hydrophilic characteristics with moisture content and uptake values reflecting their water-absorbing capacity, while films with 30% GLY and 5% CCE exhibit enhanced hydrophobicity. In addition, CCE characterization reveals significant polyphenol content (734.45 mg GAE/g), highlighting its antioxidant capacity. Moreover, CCE supplies remarkable antioxidant properties to the films. These findings suggest the potential of these bioplastics for industrial applications as a sustainable solution to traditional plastics and in reducing environmental impact while preventing oxidative reactions in packaged products.
对生物塑料中自然资源的探索推动了生物基材料的发展。利用流延法,制备了含有不同甘油(GLY)百分比(相对于壳聚糖(CH)为0至50%)和富含花青素的馏分(相对于CH为0至5%)的酸化乙醇提取物(CCE)的壳聚糖基薄膜。CCE是一种观赏植物,以其具有健康益处的生物活性化合物而闻名。水胶体薄膜表现出良好的机械性能。含30% GLY + 5% CCE的薄膜的断裂伸长率达到57.4%,与含50% GLY的薄膜相当,同时具有更高的拉伸强度和杨氏模量。富含抗氧化剂的CCE起到了增塑剂的作用,提高了薄膜的柔韧性和可加工性。薄膜表现出亲水性,其水分含量和吸湿值反映了它们的吸水能力,而含30% GLY和5% CCE的薄膜表现出增强的疏水性。此外,CCE的表征显示其具有显著的多酚含量(734.45 mg GAE/g),突出了其抗氧化能力。而且,CCE为薄膜提供了显著的抗氧化性能。这些发现表明这些生物塑料在工业应用中具有潜力,可作为传统塑料的可持续解决方案,减少环境影响,同时防止包装产品中的氧化反应。