Aleksanyan Kristine V, Smykovskaya Regina S, Samoilova Nadezhda A, Novikov Viktor A, Shakhov Aleksander M, Aybush Arseny V, Kuznetsova Olga P, Lomakin Sergey M, Ryzhmanova Yana V
Higher Engineering School "New Materials and Technologies", Plekhanov Russian University of Economics, 36 Stremyanny Ln, Moscow 117997, Russia.
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 4 Kosygina St., Moscow 119991, Russia.
Polymers (Basel). 2024 Sep 29;16(19):2758. doi: 10.3390/polym16192758.
Nowadays, the demand for food packaging that maintains the safety and quality of products has become one of the leading challenges. It can be solved by developing functional materials based on biodegradable polymers, such as poly(lactic acid) (PLA). In order to develop PLA-based functional materials with antibacterial activity, silver nanoparticles (AgNPs) were introduced. In the present study, AgNPs stabilized by a copolymer of ethylene and maleic acid were used. Under the joint action of shear deformations and high temperature, the biocomposites of PLA with poly(ethylene glycol) and AgNPs were produced. Their mechanical and thermal characteristics, water absorption, and structure were investigated using modern methods (DSC, FTIR, Raman spectroscopy, SEM). The effect of AgNP concentration on the characteristics of PLA-based biocomposites was detected. Based on the results of antibacterial activity tests (against Gram-positive and Gram-negative bacteria, along with yeast) it is assumed that these systems have potential as materials for extending the storage of food products. At the same time, PLA-PEG biocomposites with AgNPs possess biodegradability.
如今,对保持产品安全和质量的食品包装的需求已成为主要挑战之一。这可以通过开发基于可生物降解聚合物的功能材料来解决,例如聚乳酸(PLA)。为了开发具有抗菌活性的基于PLA的功能材料,引入了银纳米颗粒(AgNP)。在本研究中,使用了由乙烯和马来酸共聚物稳定的AgNP。在剪切变形和高温的共同作用下,制备了PLA与聚乙二醇和AgNP的生物复合材料。使用现代方法(DSC、FTIR、拉曼光谱、SEM)研究了它们的机械和热特性、吸水性和结构。检测了AgNP浓度对基于PLA的生物复合材料特性的影响。基于抗菌活性测试结果(针对革兰氏阳性和革兰氏阴性细菌以及酵母),推测这些体系有潜力作为延长食品储存期的材料。同时,含有AgNP的PLA-PEG生物复合材料具有生物可降解性。