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多离子印迹聚合物合成的多重挑战

The Multi-Challenges of the Multi-Ion-Imprinted Polymer Synthesis.

作者信息

Zepeda-Navarro Abraham, Segoviano-Garfias José J N, Bivián-Castro Egla Yareth

机构信息

Centro Universitario de los Lagos, Universidad de Guadalajara, Av. Enrique Díaz de León 1144, Col. Paseos de la Montaña, Lagos de Moreno 47460, Jalisco, Mexico.

División de Ciencias de la Vida, Carr. Irapuato-Silao Km. 12.5, Ex-Hacienda El Copal, Irapuato 36821, Guanajuato, Mexico.

出版信息

Polymers (Basel). 2024 Oct 3;16(19):2804. doi: 10.3390/polym16192804.

DOI:10.3390/polym16192804
PMID:39408513
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11478749/
Abstract

Multi-ion-imprinted polymers (MIIPs) are materials with a wide range of applications mainly focused on environmental recovery, mining, technology, sensors, etc. MIIPs can incorporate ions such as heavy metals, transition metals, rare earth elements, radionuclides, and other types of ions. The chemical structures of MIIPs can be designed for different purposes and with certain morphologies, such as gels, crystals, or powders, and the surface area and porosity are also considered. All these properties provide the material with several desirable characteristics, like high selectivity, high specificity, adequate efficiency, good stability, the possibility of reusability, and strategy technology adaptation. In this review, we show the multitude of challenges of multi-ion imprinted polymer chemical synthesis based on the different and interesting methods reported previously.

摘要

多离子印迹聚合物(MIIPs)是一类具有广泛应用的材料,主要集中在环境修复、采矿、技术、传感器等领域。MIIPs可以结合重金属、过渡金属、稀土元素、放射性核素等多种离子以及其他类型的离子。MIIPs的化学结构可根据不同目的进行设计,并具有特定的形态,如凝胶、晶体或粉末,同时还会考虑其表面积和孔隙率。所有这些特性赋予了该材料若干理想的性能,如高选择性、高特异性、足够的效率、良好的稳定性、可重复使用的可能性以及对策略技术的适应性。在本综述中,我们基于先前报道的不同且有趣的方法,展示了多离子印迹聚合物化学合成面临的众多挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f520/11478749/0c77b1431114/polymers-16-02804-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f520/11478749/0c77b1431114/polymers-16-02804-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f520/11478749/0c77b1431114/polymers-16-02804-g001.jpg

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Dummy molecularly imprinted polymer-based solid-phase extraction method for the determination of some phthalate monoesters in urine by gas chromatography-mass spectrometry analysis.基于 dummy 分子印迹聚合物的固相萃取法,结合气相色谱-质谱分析法,用于尿液中某些邻苯二甲酸单酯的测定。
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A biobased magnetic dual-dummy-template molecularly imprinted polymer using a deep eutectic solvent as a coporogen for highly selective enrichment of organophosphates.一种基于生物的磁性双虚拟模板分子印迹聚合物,使用深共晶溶剂作为共溶剂,用于有机磷的高选择性富集。
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