Zhang Nan, Wang Xichen, Sun Pei, Zheng Nanxiang, Sun Aodi
School of Urban Construction and Transportation, Hefei University, Hefei 230601, China.
Anhui Provincial Key Laboratory of Urban Rail Transit Safety and Emergency Management, Hefei University, Hefei 230601, China.
Polymers (Basel). 2024 Oct 9;16(19):2850. doi: 10.3390/polym16192850.
In this study, the feasibility of using bamboo bark fibers as modifiers to enhance asphalt mortar performance was investigated. Bamboo bark fibers were modified with NaOH, KH570 silane coupling agent, and nano-SiO, and their preparation methods were established. The modified fibers were assessed for their oil absorption, thermal stability, and hydrophobicity. The asphalt mortar was evaluated for three key indicators: rutting resistance, deformation resistance, and durability at high temperatures. The microscopic morphology and modification mechanisms of the fibers were also studied. The results showed that modification with NaOH increased fiber porosity and surface roughness, while KH570 and its hydrolysis products enabled nano-SiO grafting onto the fibers, improving their adsorption to asphalt. The NaOH-KH570-nano-SiO ternary-composite-modified bamboo bark fiber (NKSBF) demonstrated superior hydrophobicity, oil absorption, and thermal stability at the asphalt mixing temperature. Among the modified fibers, asphalt mortar containing 3% NKSBF showed the best performance based on three key indicators, increased the shear strength by 96.4% and the softening point by 7.1% compared to the base asphalt, and increased the ductility by 1% compared to lignin fiber asphalt mortar. The incorporation of 3% bamboo bark fibers improved the rutting resistance, deformation resistance, and durability of short-term-aged asphalt mortar, with NKSBF showing the most significant improvement.
本研究考察了使用竹皮纤维作为改性剂来提高沥青胶浆性能的可行性。用氢氧化钠、KH570硅烷偶联剂和纳米二氧化硅对竹皮纤维进行改性,并确定了其制备方法。对改性纤维的吸油率、热稳定性和疏水性进行了评估。对沥青胶浆的三项关键指标进行了评价:抗车辙性、抗变形性和高温耐久性。还研究了纤维的微观形态和改性机理。结果表明,用氢氧化钠改性增加了纤维的孔隙率和表面粗糙度,而KH570及其水解产物使纳米二氧化硅接枝到纤维上,提高了它们对沥青的吸附能力。氢氧化钠-KH570-纳米二氧化硅三元复合改性竹皮纤维(NKSBF)在沥青搅拌温度下表现出优异的疏水性、吸油率和热稳定性。在改性纤维中,含3%NKSBF的沥青胶浆在三项关键指标方面表现最佳,与基质沥青相比,抗剪强度提高了96.4%,软化点提高了7.1%,与木质素纤维沥青胶浆相比,延度提高了1%。掺入3%的竹皮纤维改善了短期老化沥青胶浆的抗车辙性、抗变形性和耐久性,其中NKSBF的改善最为显著。