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一种用于植物生长监测的高灵敏度、低蠕变水凝胶传感器。

A Highly Sensitive, Low Creep Hydrogel Sensor for Plant Growth Monitoring.

机构信息

Province Key Laboratory of Forestry Intelligent Equipment Engineering, College of Mechanical and Electrical Engineering, Northeast Forestry University, Harbin 150000, China.

出版信息

Sensors (Basel). 2024 Sep 25;24(19):6197. doi: 10.3390/s24196197.

Abstract

Ion-conducting hydrogels show significant potential in plant growth monitoring. Nevertheless, traditional ionic hydrogel sensors experience substantial internal creep and inadequate sensitivity, hindering precise plant growth monitoring. In this study, we developed a flexible hydrogel sensor composed of polyvinyl alcohol and acrylamide. The hydrogel sensor exhibits low creep and high sensitivity. Polyvinyl alcohol, acrylamide, and glycerol are crosslinked to create a robust interpenetrating double network structure. The strong interactions, such as van der Waals forces, between the networks minimize hydrogel creep under external stress, reducing the drift ratio by 50% and the drift rate by more than 60%. Additionally, sodium chloride and AgNWs enrich the hydrogel with conductive ions and pathways, enhancing the sensor's conductivity and demonstrating excellent response time (0.4 s) and recovery time (0.3 s). When used as a sensor for plant growth monitoring, the sensor exhibits sensitivity to small strains and stability for long-term monitoring. This sensor establishes a foundation for developing plant health monitoring systems utilizing renewable biomass materials.

摘要

离子传导水凝胶在植物生长监测方面具有重要的应用潜力。然而,传统的离子水凝胶传感器存在较大的内蠕变和灵敏度不足的问题,限制了其在植物生长监测方面的应用。本研究制备了一种由聚乙烯醇和丙烯酰胺组成的柔性水凝胶传感器。该水凝胶传感器具有低蠕变和高灵敏度的特点。通过聚乙烯醇、丙烯酰胺和甘油交联形成了稳定的互穿双网络结构。网络之间的强相互作用(如范德华力)可最大程度地减少水凝胶在外力作用下的蠕变,使漂移率降低 50%,漂移速度降低 60%以上。此外,氯化钠和 AgNWs 为水凝胶提供了丰富的导电离子和通道,提高了传感器的导电性,表现出优异的响应时间(0.4 s)和恢复时间(0.3 s)。将其用作植物生长监测传感器时,该传感器对小应变具有灵敏度,并且能够进行长期稳定监测。该传感器为利用可再生生物质材料开发植物健康监测系统奠定了基础。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a799/11478791/c50a14ade36e/sensors-24-06197-g001.jpg

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