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来自消费后废弃物的再生低密度聚乙烯与机械和热降解相关的性能

Mechanical and Thermal Degradation-Related Performance of Recycled LDPE from Post-Consumer Waste.

作者信息

Müller Miroslav, Kolář Viktor, Mishra Rajesh Kumar

机构信息

Department of Material Science and Manufacturing Technology, Faculty of Engineering, Czech University of Life Sciences Prague, 165 00 Prague, Czech Republic.

出版信息

Polymers (Basel). 2024 Oct 10;16(20):2863. doi: 10.3390/polym16202863.

Abstract

This paper presents research aimed at laboratory experiments on static and cyclic fatigue testing of low-density polyethylene (LDPE) recovered from post-consumer waste in order to develop a recycled product exhibiting satisfactory mechanical and thermo-mechanical properties. The results of the cyclic fatigue tests set up to 80% of the maximum load in static tensile testing demonstrated satisfactory functionality of the recycled material developed by using the injection molding process. There was no significant change in the tensile strength under static and cyclic fatigue tests. Under cyclic loading, there was a quasi-static effect manifested by plastic deformation, and the displacement increased significantly. The static and cyclic tensile tests indicated improvement in the mechanical performance of the recycled LDPE as compared to the virgin material, owing to the high quality of the regranulates. Fourier Transform Infrared Spectroscopy (FTIR) was conducted to analyze the functional groups in virgin and recycled LDPE samples. The analysis showed no significant change in the transmittance spectra. The thermal degradation performance was also analyzed by Differential Scanning Calorimetry (DSC) and Dynamic Mechanical Analysis (DMA). The results were quite similar for both virgin and recycled LDPE.

摘要

本文介绍了旨在对从消费后废弃物中回收的低密度聚乙烯(LDPE)进行静态和循环疲劳测试的实验室实验研究,以开发出具有令人满意的机械和热机械性能的再生产品。在静态拉伸测试中,循环疲劳测试设定为最大载荷的80%,结果表明通过注塑工艺开发的再生材料具有令人满意的功能。在静态和循环疲劳测试下,拉伸强度没有显著变化。在循环加载下,出现了由塑性变形表现出的准静态效应,位移显著增加。静态和循环拉伸测试表明,由于再生颗粒的高质量,与原始材料相比,再生LDPE的机械性能有所提高。进行了傅里叶变换红外光谱(FTIR)分析,以分析原始和再生LDPE样品中的官能团。分析表明,透射光谱没有显著变化。还通过差示扫描量热法(DSC)和动态力学分析(DMA)对热降解性能进行了分析。原始和再生LDPE的结果非常相似。

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