Yue Xuejie, Xu Kangning, Wang Shuyi, Liu Hengyan, Guo Shiyue, Zhao Rusheng, Xu Gaopeng, Wang Hao, Yue Xuezheng
School of Civil Engineering and Architecture, Xinxiang College, Xinxiang 453000, China.
Department of Material Science and Chemical, University of Shanghai for Science and Technology, Shanghai 200093, China.
Materials (Basel). 2024 Oct 12;17(20):4988. doi: 10.3390/ma17204988.
In this study, we utilized Selective Laser Melting (SLM) technology to fabricate a magnesium alloy, and subsequently subject it to micro-arc oxidation treatment. We analyzed and compared the microstructure, elemental distribution, wetting angle, and corrosion resistance of the SLM magnesium alloy both before and after the micro-arc oxidation process. The findings indicate that the SLM magnesium alloy exhibits surface porosity defects ranging from 2% to 3.2%, which significantly influence the morphology and functionality of the resulting film layer formed during the micro-arc oxidation process. These defects manifest as pores on the surface, leading to an uneven distribution of micropores with varying sizes across the layer. The surface roughness of the 3D-printed magnesium alloy exhibits a high roughness value of 180 nanometers. The phosphorus (P) content is lower within the film layer compared to the surface, suggesting that the Mg(PO) phase predominantly resides on the surface, whereas the interior is primarily composed of MgO. The micro-arc oxidation process enhances the hydrophilicity and corrosion resistance of the SLM magnesium alloy, thereby potentially endowing it with bioactivity. Additionally, the increased surface roughness post-treatment promotes cell proliferation. However, certain inherent defects present in the SLM magnesium alloy samples negatively impact the improvement of their corrosion resistance.
在本研究中,我们利用选择性激光熔化(SLM)技术制备了一种镁合金,随后对其进行微弧氧化处理。我们分析并比较了微弧氧化处理前后SLM镁合金的微观结构、元素分布、润湿性和耐腐蚀性。研究结果表明,SLM镁合金存在2%至3.2%的表面孔隙率缺陷,这对微弧氧化过程中形成的最终膜层的形态和功能有显著影响。这些缺陷表现为表面的孔隙,导致整个层中微孔大小分布不均。3D打印镁合金的表面粗糙度呈现出180纳米的高粗糙度值。与表面相比,膜层中的磷(P)含量较低,这表明Mg(PO)相主要存在于表面,而内部主要由MgO组成。微弧氧化过程增强了SLM镁合金的亲水性和耐腐蚀性,从而可能赋予其生物活性。此外,处理后表面粗糙度的增加促进了细胞增殖。然而,SLM镁合金样品中存在的某些固有缺陷对其耐腐蚀性的改善产生了负面影响。