Frías Moisés, Moreno de Los Reyes Ana María, Villar-Cociña Ernesto, García Rosario, Vigil de la Villa Raquel, Vasić Milica Vidak
Eduardo Torroja Institute for Construction Sciences, IETcc-CSIC, 28033 Madrid, Spain.
Department of Physics, Universidad Central de las Villas, Santa Clara 54830, Cuba.
Materials (Basel). 2024 Oct 14;17(20):5012. doi: 10.3390/ma17205012.
Biomass ash is currently attracting the attention of science and industry as an inexhaustible eco-friendly alternative to pozzolans traditionally used in commercial cement manufacture (fly ash, silica fume, natural/calcined pozzolan). This paper explores a new line of research into Marabou weed ash (MA), an alternative to better-known conventional agro-industry waste materials (rice husk, bagasse cane, bamboo, forest waste, etc.) produced in Cuba from an invasive plant harvested as biomass for bioenergy production. The study entailed full characterization of MA using a variety of instrumental techniques, analysis of pozzolanic reactivity in the pozzolan/lime system, and, finally its influence on the physical and mechanical properties of binary pastes and mortars containing 10% and 20% MA replacement content. The results indicate that MA has a very low acid oxide content and a high loss on ignition (30%) and KO content (6.9%), which produces medium-low pozzolanic activity. Despite an observed increase in the blended mortars' total and capillary water absorption capacity and electrical resistivity and a loss in mechanical strength approximately equivalent to the replacement percentage, the 10% and 20% MA blended cements meet the regulatory chemical, physical, and mechanical requirements specified. Marabou weed ash is therefore a viable future supplementary cementitious material.
生物质灰作为传统用于商业水泥生产的火山灰质材料(粉煤灰、硅灰、天然/煅烧火山灰)的一种取之不尽的环保替代品,目前正吸引着科学界和工业界的关注。本文探索了一条关于鹳草灰(MA)的新研究路线,鹳草灰是古巴利用一种作为生物质收获用于生物能源生产的入侵植物生产的,它可替代更为人熟知的传统农业工业废料(稻壳、甘蔗渣、竹子、森林废料等)。该研究包括使用多种仪器技术对MA进行全面表征,分析火山灰/石灰体系中的火山灰反应活性,最后研究其对含10%和20%MA替代量的二元浆体和砂浆的物理和力学性能的影响。结果表明,MA的酸性氧化物含量非常低,烧失量高(30%),KO含量高(6.9%),这导致其火山灰活性为中低水平。尽管观察到混合砂浆的总吸水率、毛细吸水率和电阻率有所增加,且力学强度损失大致相当于替代百分比,但含10%和20%MA的混合水泥符合规定的化学、物理和力学要求。因此,鹳草灰是一种可行的未来辅助胶凝材料。